1-(4'-bromobenzyl)pyridinium bis(1,2-benzenedithiolato)nickel(III)

Base Information

• Chemical Name: 1-(4'-bromobenzyl)pyridinium bis(1,2-benzenedithiolato)nickel(III)
• CAS No.: 518291-00-4
• Molecular Formula: C₁₂H₈NiS₄*C₁₂H₁₁BrN
• Molecular Weight: 588.28
• Mol file: 518291-00-4.mol

Synonyms:

Chemical Property of 1-(4'-bromobenzyl)pyridinium bis(1,2-benzenedithiolato)nickel(III)

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of 1-(4'-bromobenzyl)pyridinium bis(1,2-benzenedithiolato)nickel(III)

There total 1 articles about 1-(4'-bromobenzyl)pyridinium bis(1,2-benzenedithiolato)nickel(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

nickel(II) chloride hexahydrate + 1-(4'-bromobenzyl)pyridinium bromide (125713-97-5) + Benzene-1,2-dithiol (17534-15-5) → 1-(4'-bromobenzyl)pyridinium bis(1,2-benzenedithiolato)nickel(III) (518291-00-4)

Guidance literature:

With air; sodium; In ethanol; under N2 at room temp. dithiol added to a soln. of Na, a soln. of Ni compd. added, F compd. added, stirred for 1 h, stirred for 24 h in air; ppt. washed (abs. ethanol, ether), dried recrystd. (twice, CH2Cl2); elem. anal.;

DOI:10.1016/S0277-5387(02)01334-7

upstream raw materials:

1-(4'-bromobenzyl)pyridinium bromide

Benzene-1,2-dithiol