[(2S,3R,4R,5S,6R)-2-((1R,2S,3S,4R,5S,6R)-2-Benzyloxycarbonylamino-3,5,6-trihydroxy-4-nitro-cyclohexyloxy)-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl]-carbamic acid benzyl ester

Base Information

Chemical Name:[(2S,3R,4R,5S,6R)-2-((1R,2S,3S,4R,5S,6R)-2-Benzyloxycarbonylamino-3,5,6-trihydroxy-4-nitro-cyclohexyloxy)-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl]-carbamic acid benzyl ester
CAS No.:85502-93-8
Molecular Formula:C₂₈H₃₅N₃O₁₄
Molecular Weight:637.598
Hs Code.:

[(2S,3R,4R,5S,6R)-2-((1R,2S,3S,4R,5S,6R)-2-Benzyloxycarbonylamino-3,5,6-trihydroxy-4-nitro-cyclohexyloxy)-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl]-carbamic acid benzyl ester

Synonyms:

Suppliers and Price of [(2S,3R,4R,5S,6R)-2-((1R,2S,3S,4R,5S,6R)-2-Benzyloxycarbonylamino-3,5,6-trihydroxy-4-nitro-cyclohexyloxy)-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl]-carbamic acid benzyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [(2S,3R,4R,5S,6R)-2-((1R,2S,3S,4R,5S,6R)-2-Benzyloxycarbonylamino-3,5,6-trihydroxy-4-nitro-cyclohexyloxy)-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl]-carbamic acid benzyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [(2S,3R,4R,5S,6R)-2-((1R,2S,3S,4R,5S,6R)-2-Benzyloxycarbonylamino-3,5,6-trihydroxy-4-nitro-cyclohexyloxy)-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl]-carbamic acid benzyl ester

There total 11 articles about [(2S,3R,4R,5S,6R)-2-((1R,2S,3S,4R,5S,6R)-2-Benzyloxycarbonylamino-3,5,6-trihydroxy-4-nitro-cyclohexyloxy)-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl]-carbamic acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 22.0%

: 75-52-5
nitromethane

: 85464-58-0,85551-12-8
Acetic acid (3S,4R,5R,6S)-2-acetoxy-5-benzyloxycarbonylamino-4-((2S,3R,4R,5S,6R)-4,5-diacetoxy-6-acetoxymethyl-3-benzyloxycarbonylamino-tetrahydro-pyran-2-yloxy)-6-methoxy-tetrahydro-pyran-3-yl ester

: 85502-93-8
[(2S,3R,4R,5S,6R)-2-((1R,2S,3S,4R,5S,6R)-2-Benzyloxycarbonylamino-3,5,6-trihydroxy-4-nitro-cyclohexyloxy)-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl]-carbamic acid benzyl ester

Guidance literature:: With sodium methylate; In methanol; for 36h; Ambient temperature;
DOI:10.1016/S0040-4039(00)85695-6

Reference yield:

: Acetic acid (2R,3S,4R,5R,6S)-5-benzyloxycarbonylamino-4-((2S,3R,4R,5S,6R)-4,5-diacetoxy-6-acetoxymethyl-3-benzyloxycarbonylamino-tetrahydro-pyran-2-yloxy)-2-hydroxymethyl-6-methoxy-tetrahydro-pyran-3-yl ester

: 85502-93-8
[(2S,3R,4R,5S,6R)-2-((1R,2S,3S,4R,5S,6R)-2-Benzyloxycarbonylamino-3,5,6-trihydroxy-4-nitro-cyclohexyloxy)-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl]-carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: CrO₃, H₂SO₄ / 3 h / Ambient temperature

2: benzene; pyridine / 3.5 h / Heating

3: 22 percent / 1percent NaOMe / methanol / 36 h / Ambient temperature

With chromium(VI) oxide; sulfuric acid; sodium methylate; In pyridine; methanol; benzene;
DOI:10.1016/S0040-4039(00)85695-6

Reference yield:

: 85502-91-6
Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-6-((2S,3R,4R,5S,6R)-3-benzyloxycarbonylamino-5-hydroxy-6-hydroxymethyl-2-methoxy-tetrahydro-pyran-4-yloxy)-5-(2,4-dinitro-phenylamino)-tetrahydro-pyran-4-yl ester

: 85502-93-8
[(2S,3R,4R,5S,6R)-2-((1R,2S,3S,4R,5S,6R)-2-Benzyloxycarbonylamino-3,5,6-trihydroxy-4-nitro-cyclohexyloxy)-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl]-carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: pyridine / 2 h / Ambient temperature

2: Dowex 1x2 (OH(-)) / acetone / 12 h / Ambient temperature

3: aq.sat. NaHCO₃ / dioxane / 1.33 h / Ambient temperature

4: pyridine, 4-dimethylaminopyridine / 12 h / Ambient temperature

5: BF_3.OEt₂ / tetrahydrofuran; diethyl ether / 1 h / Ambient temperature

6: CrO₃, H₂SO₄ / 3 h / Ambient temperature

7: benzene; pyridine / 3.5 h / Heating

8: 22 percent / 1percent NaOMe / methanol / 36 h / Ambient temperature

With pyridine; chromium(VI) oxide; dmap; Dowex 1x2 (OH(-)); sulfuric acid; boron trifluoride diethyl etherate; sodium methylate; sodium hydrogencarbonate; In tetrahydrofuran; 1,4-dioxane; pyridine; methanol; diethyl ether; acetone; benzene;
DOI:10.1016/S0040-4039(00)85695-6