silver dicyclohexylphosphinate

Base Information

• Chemical Name: silver dicyclohexylphosphinate
• CAS No.: 116052-71-2
• Molecular Formula: Ag*C₁₂H₂₂O₂P
• Molecular Weight: 337.147
• Mol file: 116052-71-2.mol

Synonyms:

Chemical Property of silver dicyclohexylphosphinate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of silver dicyclohexylphosphinate

There total 1 articles about silver dicyclohexylphosphinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dicyclohexylphosphinic acid (832-39-3) + silver nitrate → silver dicyclohexylphosphinate (116052-71-2)

Guidance literature:

With NaOH; In water; N2-atmosphere; treatment of phosphinic acid with stoich. amt. of NaOH, pptn. on addn. of AgNO3; filtration, washing (MeOH), drying (vac.);

DOI:10.1039/DT9950002151

Reference yield: 64.0%

silver dicyclohexylphosphinate (116052-71-2) + diphenylantimony trichloride (21907-22-2) → (Sb(C6H5)2Cl(O2P(C6H11)2))2O

Guidance literature:

With H₂O; In toluene; byproducts: AgCl, HCl; N2-atmosphere; refluxing of Sb-compd. with 2 equiv. of phosphinate (2 h); filtration, solvent removal, crystn. (CH2Cl2/hexane=1:5); elem. anal.;

DOI:10.1039/DT9950002151

Reference yield: 60.0%

silver dicyclohexylphosphinate (116052-71-2) + dibenzyltin(IV) dichloride (3002-01-5) → [Sn(CH2C6H5)(OH)(O2P(C6H11)2)2]2

Guidance literature:

In toluene; (N2); reflux (12 h); filtration, solvent removal, dossoln. (CH2Cl2), filtration, concn., pptn. upon addn. of n-heptane; elem. anal.;

upstream raw materials:

dicyclohexylphosphinic acid

Downstream raw materials:

dimeric n-butyloxotin bis(dicyclohexylphosphinate)

{((C₄H₉)Sn(OH)O₂P(C₆H₁₁)2)3O}⁽¹⁺⁾*{(C₆H₁₁)2PO₂}^(1-)={((C₄H₉)Sn(OH)O₂P(C₆H₁₁)2)3O}{(C₆H₁₁)2PO₂}