[2,7-bis(1,1-dimethylethyl)-9,9-dimethyl-4,5-bis(1-(2,3-dimethylphenylamino)-3-(2,3-dimethylphenylimino)isopropenyl)xanthene](ethylzinc)2

Base Information

• Chemical Name: [2,7-bis(1,1-dimethylethyl)-9,9-dimethyl-4,5-bis(1-(2,3-dimethylphenylamino)-3-(2,3-dimethylphenylimino)isopropenyl)xanthene](ethylzinc)2
• CAS No.: 945683-71-6
• Molecular Formula: C₆₅H₇₈N₄OZn₂
• Molecular Weight: 1062.14
• Mol file: 945683-71-6.mol

Synonyms:

Chemical Property of [2,7-bis(1,1-dimethylethyl)-9,9-dimethyl-4,5-bis(1-(2,3-dimethylphenylamino)-3-(2,3-dimethylphenylimino)isopropenyl)xanthene](ethylzinc)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [2,7-bis(1,1-dimethylethyl)-9,9-dimethyl-4,5-bis(1-(2,3-dimethylphenylamino)-3-(2,3-dimethylphenylimino)isopropenyl)xanthene](ethylzinc)2

There total 1 articles about [2,7-bis(1,1-dimethylethyl)-9,9-dimethyl-4,5-bis(1-(2,3-dimethylphenylamino)-3-(2,3-dimethylphenylimino)isopropenyl)xanthene](ethylzinc)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

2,7-bis(1,1-dimethylethyl)-9,9-dimethyl-4,5-bis(1-(2,3-dimethylphenylamino)-3-(2,3-dimethylphenylimino)isopropenyl)xanthene (896711-16-3) + diethylzinc (557-20-0) → [2,7-bis(1,1-dimethylethyl)-9,9-dimethyl-4,5-bis(1-(2,3-dimethylphenylamino)-3-(2,3-dimethylphenylimino)isopropenyl)xanthene](ethylzinc)2 (945683-71-6)

Guidance literature:

In tetrahydrofuran; (under Ar, Schlenk); ligand dissolved in THF, Zn(CH2CH3)2 added, stirredovernight; volatiles removed under vac., ppt. dissolved in Et2O, volatiles removed under vac.; elem. anal.;

DOI:10.1021/om070221e

Reference yield: 99.0%

[2,7-bis(1,1-dimethylethyl)-9,9-dimethyl-4,5-bis(1-(2,3-dimethylphenylamino)-3-(2,3-dimethylphenylimino)isopropenyl)xanthene](ethylzinc)2 (945683-71-6) + sulfur dioxide (7446-09-5,12143-17-8,89125-89-3) → [2,7-bis(1,1-dimethylethyl)-9,9-dimethyl-4,5-bis(1-(2,3-dimethylphenylamino)-3-(2,3-dimethylphenylimino)isopropenyl)xanthene](ZnSO2Et)2

Guidance literature:

In tetrahydrofuran; (under Ar, Schlenk); Zn-complex dissolved in THF, cooled to -30°C, evacuated, SO2 condensed, stirred for 30 min at -30°C, warmed to room temp.; volatiles removed under vac.; elem. anal.;

DOI:10.1021/om070221e

upstream raw materials:

2,7-bis(1,1-dimethylethyl)-9,9-dimethyl-4,5-bis(1-(2,3-dimethylphenylamino)-3-(2,3-dimethylphenylimino)isopropenyl)xanthene

diethylzinc