[(ruthenium)(hydride)(bis(1,2-diphenylphosphinoethane)](trifluoromethanesulfonate)

Base Information

Chemical Name:[(ruthenium)(hydride)(bis(1,2-diphenylphosphinoethane)](trifluoromethanesulfonate)
CAS No.:356528-38-6
Molecular Formula:CF₃O₃S*C₅₂H₄₉P₄Ru
Molecular Weight:1048
Hs Code.:

Synonyms:

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Chemical Property of [(ruthenium)(hydride)(bis(1,2-diphenylphosphinoethane)](trifluoromethanesulfonate)

Chemical Property:

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Technology Process of [(ruthenium)(hydride)(bis(1,2-diphenylphosphinoethane)](trifluoromethanesulfonate)

There total 1 articles about [(ruthenium)(hydride)(bis(1,2-diphenylphosphinoethane)](trifluoromethanesulfonate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 915234-68-3
[(ruthenium)(hydride)(bis(1,2-diphenylphosphinoethane)]BF₄

: 2926-27-4
potassium trifluoromethansulfonate

: 356528-38-6,915234-66-1
[(ruthenium)(hydride)(bis(1,2-diphenylphosphinoethane)](trifluoromethanesulfonate)

Guidance literature:: In tetrahydrofuran; byproducts: KBF4; (under Ar, Schlenk); Ru-complex in THF treated with KCF3SO3; filtered;
DOI:10.1021/ja0651198

Reference yield: 93.3%

: 356528-38-6,915234-66-1
[(ruthenium)(hydride)(bis(1,2-diphenylphosphinoethane)](trifluoromethanesulfonate)

: 919765-93-8
2,2,2-triphenylmethylphosphaalkyne

: RuH(bis(1,2-diphenylphosphino)ethane)2(Ph₃CCP)OTf

Guidance literature:: In tetrahydrofuran; (under Ar, Schlenk); Ru-complex dissolved in THF, ligand in THF added, stirred for 10 min; filtered, concd., layered with toluene, evapd. slowly, 1 d, mother liquor removed, ppt. washed with THF, solvent removed under reduced pressure;elem. anal.;
DOI:10.1021/ja0651198

Reference yield: 84.5%

: 915234-59-2
(triphenylsilanyl)-methylidyne-phosphane

: 356528-38-6,915234-66-1
[(ruthenium)(hydride)(bis(1,2-diphenylphosphinoethane)](trifluoromethanesulfonate)

: η1-[ruthenium(hydride)(bis(1,2-diphenylphosphinoethane))2((phenyl)3SiCP)](trifluoromethanesulfonate)

Guidance literature:: In dichloromethane; toluene; under Ar, Schlenk techniques; soln. of PCSi(C6H5)3 (1 mmol) (toluene) added to soln. of Ru complex (0.5 mmol) (CH2Cl2); soln. concd. for 1 h (under reduced pressure), suspn. mixed for 2 h, filtered, washed (diethyl ether), excess of solvent removed (under reduced pressure); crystd. from THF/toluene;
DOI:10.1002/anie.200602499