4,4'-bis[P-(2,6-bis((dimethylamino)methyl)phenylgold(I))diphenylphosphino]biphenyl toluene solvate

Base Information

• Chemical Name: 4,4'-bis[P-(2,6-bis((dimethylamino)methyl)phenylgold(I))diphenylphosphino]biphenyl toluene solvate
• CAS No.: 945657-54-5
• Molecular Formula: C₇H₈*C₆₀H₆₆Au₂N₄P₂
• Molecular Weight: 1391.23
• Mol file: 945657-54-5.mol

Synonyms:

Chemical Property of 4,4'-bis[P-(2,6-bis((dimethylamino)methyl)phenylgold(I))diphenylphosphino]biphenyl toluene solvate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,4'-bis[P-(2,6-bis((dimethylamino)methyl)phenylgold(I))diphenylphosphino]biphenyl toluene solvate

There total 4 articles about 4,4'-bis[P-(2,6-bis((dimethylamino)methyl)phenylgold(I))diphenylphosphino]biphenyl toluene solvate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

2,6-bis[(dimethylamino)methyl]phenyllithium (313963-74-5) + 4,4'-bis[P-(chlorogold(I))diphenylphosphino]biphenyl (528522-58-9) + toluene (108-88-3,15644-74-3,16713-13-6) → 4,4'-bis[P-(2,6-bis((dimethylamino)methyl)phenylgold(I))diphenylphosphino]biphenyl toluene solvate (945657-54-5)

Guidance literature:

In not given; (N2, Schlenk technique); reaction of gold compd. with phenyllithium deriv.; M. Stol, D.J.M. Snelders, H. Kooijman, A.L Spek, G.P.M van Klink, and G. van Koten, Dalton Trans., 2007, 2589-2593;

DOI:10.1039/c1dt10482a

Reference yield:

4,4′-bis(diphenylphosphino)biphenylene (4129-44-6) → 4,4'-bis[P-(2,6-bis((dimethylamino)methyl)phenylgold(I))diphenylphosphino]biphenyl toluene solvate (945657-54-5)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane

2: toluene

In dichloromethane; toluene;

DOI:10.1039/b701271c

Reference yield:

4,4'-bis[P-(chlorogold(I))diphenylphosphino]biphenyl (528522-58-9) → 4,4'-bis[P-(2,6-bis((dimethylamino)methyl)phenylgold(I))diphenylphosphino]biphenyl toluene solvate (945657-54-5)

Guidance literature:

Multi-step reaction with 3 steps

1: toluene

2: toluene

3: toluene

In toluene;

DOI:10.1039/b701271c

upstream raw materials:

2,6-bis[(dimethylamino)methyl]phenyllithium

4,4'-bis[P-(chlorogold(I))diphenylphosphino]biphenyl

toluene

4,4′-bis(diphenylphosphino)biphenylene

Downstream raw materials:

[Ti(C₆H₃(CH₂NMe₂)2-2,6)Cl₂(OCHMe₂)]

4,4'-bis[P-(chlorogold(I))diphenylphosphino]biphenyl

[(Au(2,6-bis(oxazolinyl)phenyl))2(4,4'-bis(diphenylphosphino)biphenyl)]

(2,6-bis[(dimethylamino)methyl]phenyl-C,N,N')niobium tetrachloride