Zn(N₄C₂₀H₈(C₆H₃(C(CH₃)3)2)3CCSi(CH₃)2Si(CH₃)2CCC₆H₄CHO)

Base Information

• Chemical Name: Zn(N₄C₂₀H₈(C₆H₃(C(CH₃)3)2)3CCSi(CH₃)2Si(CH₃)2CCC₆H₄CHO)
• CAS No.: 915717-02-1
• Molecular Formula: C₇₇H₈₈N₄OSi₂Zn
• Molecular Weight: 1207.13
• Mol file: 915717-02-1.mol

Synonyms:

Chemical Property of Zn(N₄C₂₀H₈(C₆H₃(C(CH₃)3)2)3CCSi(CH₃)2Si(CH₃)2CCC₆H₄CHO)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Zn(N₄C₂₀H₈(C₆H₃(C(CH₃)3)2)3CCSi(CH₃)2Si(CH₃)2CCC₆H₄CHO)

There total 2 articles about Zn(N₄C₂₀H₈(C₆H₃(C(CH₃)3)2)3CCSi(CH₃)2Si(CH₃)2CCC₆H₄CHO) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

Zn(N4C20H8(C6H3(C(CH3)3)2)3CCSi(CH3)2Si(CH3)2CCH) (915717-01-0) + p-(iodophenyl)carboxaldehyde (15164-44-0) → Zn(N4C20H8(C6H3(C(CH3)3)2)3CCSi(CH3)2Si(CH3)2CCC6H4CHO) (915717-02-1)

Guidance literature:

With tetrakis(triphenylphosphine)palladium; copper(I) iodide; Et₃N; In tetrahydrofuran; under N2; soln. of Zn compd. in THF deoxygenated by bubbling N2 for 30 min; IC6H4CHO, Pd(PPh3)4, CuI and Et3N added; stirred at room temp. for 12 h; evapd.; suspended in CH2Cl2; filtered through silica gel pad; evapd.; subjected to gel permeation chromy. (polystyrene gel, toluene); evapd.; subjected to column chromy. (silica gel, hexane-toluene 1:1, 1:2);

DOI:10.1246/bcsj.79.1338

Reference yield:

[5-iodo-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (220355-80-6) + 1,2-diethylnyl-1,1,2,2-tetramethyldisilane (54773-31-8) → Zn(N4C20H8(C6H3(C(CH3)3)2)3CCSi(CH3)2Si(CH3)2CCC6H4CHO) (915717-02-1)

Guidance literature:

Multi-step reaction with 2 steps

1: dichlorobis(triphenylphosphine)palladium(II); copper(I) iodide; Et₃N / tetrahydrofuran

2: tetrakis(triphenylphosphine)palladium; copper(I) iodide; Et₃N / tetrahydrofuran

With dichlorobis(triphenylphosphine)palladium(II); copper(I) iodide; Et₃N; tetrakis(triphenylphosphine)palladium; In tetrahydrofuran;

DOI:10.1246/bcsj.79.1338

Reference yield: 77.0%

sarcosine (107-97-1,25951-24-0) + Zn(N4C20H8(C6H3(C(CH3)3)2)3CCSi(CH3)2Si(CH3)2CCC6H4CHO) (915717-02-1) + fullerene-C60 (99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0) → Zn(N4C20H8(C6H3(C(CH3)3)2)3CCSi(CH3)2Si(CH3)2CCC6H4CHN(CH3)CH2C60) (915717-03-2)

Guidance literature:

In toluene; under N2; soln. of Zn compd., C60 and N-methylglycine in toluene deoxygenated by bubbling N2 for 30 min; heated under reflux and stirred in the dark for 12 h; cooled to room temp.; filtered through silica gel pad; evapd.; subjected to column chromy. (silica gel, hexane-toluene 4:1, 2:3); evapd.; subjected to gel permeation chromy. (polystyrene gel, toluene);

DOI:10.1246/bcsj.79.1338

upstream raw materials:

Zn(N₄C₂₀H₈(C₆H₃(C(CH₃)3)2)3CCSi(CH₃)2Si(CH₃)2CCH)

p-(iodophenyl)carboxaldehyde

[5-iodo-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

1,2-diethylnyl-1,1,2,2-tetramethyldisilane

Downstream raw materials:

Zn(N₄C₂₀H₈(C₆H₃(C(CH₃)3)2)3CCSi(CH₃)2Si(CH₃)2CCC₆H₄CHN(CH₃)CH₂C₆₀)

Refernces