di-chloro-bis(diethylphenylphosphine)-cobalt(II)

Base Information

Chemical Name:di-chloro-bis(diethylphenylphosphine)-cobalt(II)
CAS No.:14916-43-9
Molecular Formula:C₂₀H₃₀Cl₂CoP₂
Molecular Weight:462.305
Hs Code.:

Synonyms:

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Chemical Property of di-chloro-bis(diethylphenylphosphine)-cobalt(II)

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Technology Process of di-chloro-bis(diethylphenylphosphine)-cobalt(II)

There total 1 articles about di-chloro-bis(diethylphenylphosphine)-cobalt(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 1605-53-4
diethyl-phenyl-phosphine

: 7646-79-9,14543-09-0,16413-89-1
cobalt(II) chloride

: 14916-43-9
di-chloro-bis(diethylphenylphosphine)-cobalt(II)

Guidance literature:: In ethanol; phosphine was added to soln. of CoCl2 in ethanol; soln. was stirred for 24 h at room temp.; solvent removed (vac.); washed (pentane); dried in vac. at room temp.; extd. in continuous with boiling toluene for 24 h; concd.; pentane added;filtered; dried (vac.); elem. anal.;
DOI:10.1016/j.jorganchem.2005.02.012

Reference yield:

: 14916-43-9
di-chloro-bis(diethylphenylphosphine)-cobalt(II)

: 120311-63-9
Co(P(C₂H₅)2(C₆H₅))2Cl₃

Guidance literature:: With NOCl; In dichloromethane; dissoln. of Co-complex in minimum of dry CH2Cl2, cooling to -80°C(acetone slush), distg. NOCl into soln. (static vac.); rapid solvent removal (vac.); elem. anal.;

Reference yield:

: 14916-43-9
di-chloro-bis(diethylphenylphosphine)-cobalt(II)

: 118-74-1,67471-27-6
hexachlorobenzene

: {Co(C₆Cl₅)2(P(C₂H₅)2C₆H₅)2}

Guidance literature:: With magnesium; In tetrahydrofuran; C6Cl5MgCl was prepd. from C6Cl6 and Mg in THF under N2 using EtMgBr as initiator, the mixt. was refluxed for 20 min, cooled, added to CoCl2(PEt2Ph)2; soln. was cooled to -10°C, treated with MeOH, ppt. was filtered,washed with 1% aq. HCl and recrystd. from benzene/methanol;
DOI:10.1016/S0022-328X(00)89038-5