trans-dichlorobis[(1-cyclohexenyl)diphenylphosphine]platinum(II)

Base Information

• Chemical Name: trans-dichlorobis[(1-cyclohexenyl)diphenylphosphine]platinum(II)
• CAS No.: 332924-96-6
• Molecular Formula: C₃₆H₃₈Cl₂P₂Pt
• Molecular Weight: 798.631
• Mol file: 332924-96-6.mol

Synonyms:

Chemical Property of trans-dichlorobis[(1-cyclohexenyl)diphenylphosphine]platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of trans-dichlorobis[(1-cyclohexenyl)diphenylphosphine]platinum(II)

There total 3 articles about trans-dichlorobis[(1-cyclohexenyl)diphenylphosphine]platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

cis-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex) (183293-92-7,183506-91-4,1209494-94-9) + (1-cyclohexenyl)diphenylphosphine (82201-23-8) → trans-dichlorobis[(1-cyclohexenyl)diphenylphosphine]platinum(II) (332924-96-6,332402-19-4)

Guidance literature:

In dichloromethane; Pt complex added with stirring under Ar to a soln. of the ligand; refluxed for 0.5 h; cooled, the product pptd. with hexane, filtered off, washed with large volume of EtOH and dry Et2O, dried in vacuo; identified by elem. anal.;

Reference yield: 75.0%

cis-dichlorobis(dimethylsulfoxide)platinum(II) (75992-73-3,25794-47-2,30729-25-0,15274-33-6,22840-91-1,14568-13-9) + (1-cyclohexenyl)diphenylphosphine (82201-23-8) → cis-dichlorobis[(1-cyclohexenyl)diphenylphosphine]platinum(II) (332924-96-6,332402-19-4)

Guidance literature:

In dichloromethane; Pt complex added with stirring under Ar to a soln. of the excess of a ligand; refluxed for 0.5 h; cooled, the product pptd. with hexane, filtered off, washed with large volume of EtOH and dry Et2O, dried in vacuo; identified by elem. anal.;

Reference yield: 50.0%

cis-dichlorobis(dimethylsulfoxide)platinum(II) (75992-73-3,25794-47-2,30729-25-0,15274-33-6,22840-91-1,14568-13-9) + (1-cyclohexenyl)diphenylphosphine (82201-23-8) → trans-dichlorobis[(1-cyclohexenyl)diphenylphosphine]platinum(II) (332924-96-6,332402-19-4)

Guidance literature:

In chloroform; an excess of Pt complex added with stirring under Ar to a soln. of the ligand; refluxed for 0.5 h; cooled, the product pptd. with hexane, filtered off, washed with large volume of EtOH and dry Et2O, dried in vacuo; identified by elem. anal.;

upstream raw materials:

cis-dichlorobis(dimethylsulfoxide)platinum(II)

(1-cyclohexenyl)diphenylphosphine

cis-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex)