C₃₇H₄₄O₅SSi

Base Information

Chemical Name:C₃₇H₄₄O₅SSi
CAS No.:1607005-97-9
Molecular Formula:C₃₇H₄₄O₅SSi
Molecular Weight:628.905
Hs Code.:

C<sub>37</sub>H<sub>44</sub>O<sub>5</sub>SSi

Synonyms:

Suppliers and Price of C₃₇H₄₄O₅SSi

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C₃₇H₄₄O₅SSi

Chemical Property:

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Technology Process of C₃₇H₄₄O₅SSi

There total 7 articles about C₃₇H₄₄O₅SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1607005-93-5
phenyl 4-O-benzyl-3-O-tert-butyldimethylsilyl-6-cyano-2-O-(2-naphthylmethyl)-1-thio-α-D-mannopyranoside

: 1607005-97-9
C₃₇H₄₄O₅SSi

Guidance literature:: phenyl 4-O-benzyl-3-O-tert-butyldimethylsilyl-6-cyano-2-O-(2-naphthylmethyl)-1-thio-α-D-mannopyranoside; With diisobutylaluminium hydride; In toluene; at -78 ℃; for 0.25h; Inert atmosphere;

With hydrogenchloride; In tetrahydrofuran; water; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/jo500640n

Reference yield:

: 1250346-19-0
phenyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-2-O-(2-naphthylmethyl)-1-thio-α-D-mannopyranoside

: 1607005-97-9
C₃₇H₄₄O₅SSi

Guidance literature:: Multi-step reaction with 4 steps

1.1: borane-THF; trimethylsilyl trifluoromethanesulfonate / tetrahydrofuran; dichloromethane / 3 h / 23 °C / Inert atmosphere

2.1: pyridine; dmap / 20 h / 0 °C / Inert atmosphere

3.1: 18-crown-6 ether / acetonitrile / 24.5 h / 0.22 - 20 °C / Molecular sieve; Inert atmosphere

4.1: diisobutylaluminium hydride / toluene / 0.25 h / -78 °C / Inert atmosphere

4.2: 1 h / 20 °C / Inert atmosphere

With pyridine; dmap; borane-THF; 18-crown-6 ether; trimethylsilyl trifluoromethanesulfonate; diisobutylaluminium hydride; In tetrahydrofuran; dichloromethane; toluene; acetonitrile;
DOI:10.1021/jo500640n

Reference yield:

: 159407-19-9
phenyl 4,6-O-benzylidene-1-thio-α-D-mannopyranoside

: 1607005-97-9
C₃₇H₄₄O₅SSi

Guidance literature:: Multi-step reaction with 6 steps

1.1: triethylamine / N,N-dimethyl-formamide / 2 h / -10 °C / Inert atmosphere

2.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.33 h / Cooling with ice; Inert atmosphere

2.2: 3 h / 20 °C / Inert atmosphere

3.1: borane-THF; scandium tris(trifluoromethanesulfonate) / tetrahydrofuran; dichloromethane / 21 h / 23 °C / Inert atmosphere

4.1: pyridine; dmap / 20 h / 0 °C / Inert atmosphere

5.1: 18-crown-6 ether / acetonitrile / 24.5 h / 0.22 - 20 °C / Molecular sieve; Inert atmosphere

6.1: diisobutylaluminium hydride / toluene / 0.25 h / -78 °C / Inert atmosphere

6.2: 1 h / 20 °C / Inert atmosphere

With pyridine; dmap; borane-THF; 18-crown-6 ether; sodium hydride; diisobutylaluminium hydride; triethylamine; scandium tris(trifluoromethanesulfonate); In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; toluene; acetonitrile; mineral oil;
DOI:10.1021/jo500640n