phenyl 9-triptycyl nitroxide

Base Information

• Chemical Name: phenyl 9-triptycyl nitroxide
• CAS No.: 83051-00-7
• Molecular Formula: C₂₆H₁₈NO
• Molecular Weight: 360.435
• Mol file: 83051-00-7.mol

Synonyms:

Chemical Property of phenyl 9-triptycyl nitroxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenyl 9-triptycyl nitroxide

There total 1 articles about phenyl 9-triptycyl nitroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 7.0%

N-phenyl-9-triptycylamine (170170-07-7) → N-(9-triptycyl)-1,4-benzoquinonimine + phenyl 9-triptycyl nitroxide (83051-00-7)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 - 20 ℃; for 2h;

DOI:10.1246/bcsj.77.2273

Reference yield: 83.0%

phenyl 9-triptycyl nitroxide (83051-00-7) → N-phenyl-N-9-triptycylhydroxylamine

Guidance literature:

With phenylhydrazine; In dichloromethane; at 20 ℃; for 0.0833333h;

DOI:10.1246/bcsj.77.2273

Reference yield:

phenyl 9-triptycyl nitroxide (83051-00-7) → O-ethyl-N-phenyl-N-9-triptycylhydroxylamine

Guidance literature:

Multi-step reaction with 2 steps

1: 83 percent / phenylhydrazine / CH₂Cl₂ / 0.08 h / 20 °C

2: 82 percent / t-BuOK / diethyl ether / 0 - 20 °C

With potassium tert-butylate; phenylhydrazine; In diethyl ether; dichloromethane;

DOI:10.1246/bcsj.77.2273

upstream raw materials:

N-phenyl-9-triptycylamine