{((2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene)(bis(pyrazol-1-yl)phenylmethyl)rhodium(I)}hexafluorophosphate

Base Information

• Chemical Name: {((2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene)(bis(pyrazol-1-yl)phenylmethyl)rhodium(I)}hexafluorophosphate
• CAS No.: 153294-99-6
• Molecular Formula: C₂₀H₂₀N₄Rh*F₆P
• Molecular Weight: 564.275
• Mol file: 153294-99-6.mol

Synonyms:

Chemical Property of {((2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene)(bis(pyrazol-1-yl)phenylmethyl)rhodium(I)}hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {((2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene)(bis(pyrazol-1-yl)phenylmethyl)rhodium(I)}hexafluorophosphate

There total 1 articles about {((2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene)(bis(pyrazol-1-yl)phenylmethyl)rhodium(I)}hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

potassium hexafluorophosphate (17084-13-8) + [(norbornadiene)rhodium(I)chloride]2 (12257-42-0) + α,α-bis(pyrazol-1-yl)toluene (40848-73-5) → {((2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene)(bis(pyrazol-1-yl)phenylmethyl)rhodium(I)}hexafluorophosphate (153294-99-6)

Guidance literature:

In methanol; the azolyl-compd. is added to the Rh-complex in MeOH, the clear yellow soln. is stirred for 1 h at room temp., KPF6 is added, the mixture is stirred for 20 min; evapn. in vacuo, the concd. soln. is kept at 0°C for 24 h, crystals are filtered off and dried, elem. anal.;

DOI:10.1021/om00013a042

upstream raw materials:

potassium hexafluorophosphate

[(norbornadiene)rhodium(I)chloride]2

α,α-bis(pyrazol-1-yl)toluene