bis(acetonitrile)[1,2-bis(diphenylphosphino)-3-(4-(ethoxydimethylsilyl)phenoxy)propane]rhodium(I) tetrafluoroborate

Base Information

• Chemical Name: bis(acetonitrile)[1,2-bis(diphenylphosphino)-3-(4-(ethoxydimethylsilyl)phenoxy)propane]rhodium(I) tetrafluoroborate
• CAS No.: 87481-92-3
• Molecular Formula: BF₄*C₄₁H₄₆N₂O₂P₂RhSi
• Molecular Weight: 878.572
• Mol file: 87481-92-3.mol

Synonyms:

Chemical Property of bis(acetonitrile)[1,2-bis(diphenylphosphino)-3-(4-(ethoxydimethylsilyl)phenoxy)propane]rhodium(I) tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of bis(acetonitrile)[1,2-bis(diphenylphosphino)-3-(4-(ethoxydimethylsilyl)phenoxy)propane]rhodium(I) tetrafluoroborate

There total 1 articles about bis(acetonitrile)[1,2-bis(diphenylphosphino)-3-(4-(ethoxydimethylsilyl)phenoxy)propane]rhodium(I) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[1,2-bis(diphenylphosphino)-3-(4-(ethoxydimethylsilyl)phenoxy)propane][bicyclo[2.2.1]hepta-2,5-diene]rhodium(I) tetrafluoroborate (87481-99-0) + acetonitrile (75-05-8,26809-02-9) → bis(acetonitrile)[1,2-bis(diphenylphosphino)-3-(4-(ethoxydimethylsilyl)phenoxy)propane]rhodium(I) tetrafluoroborate (87481-92-3)

Guidance literature:

With hydrogen; In acetonitrile; under Ar; to soln. of Rh complex in MeCN added H2; not isolated, monitored by NMR and UV;

DOI:10.1021/ja00363a014

upstream raw materials:

[1,2-bis(diphenylphosphino)-3-(4-(ethoxydimethylsilyl)phenoxy)propane][bicyclo[2.2.1]hepta-2,5-diene]rhodium(I) tetrafluoroborate

acetonitrile