(-)-((R,R)-2-exo-3-endo-bis(diphenylphosphino)bicyclo[2.2.1]heptene)(norbornadiene)rhodium perchlorate

Base Information

• Chemical Name: (-)-((R,R)-2-exo-3-endo-bis(diphenylphosphino)bicyclo[2.2.1]heptene)(norbornadiene)rhodium perchlorate
• CAS No.: 78791-09-0
• Molecular Formula: C₄H₈O*C₃₈H₃₆P₂Rh
• Molecular Weight: 729.664
• Mol file: 78791-09-0.mol

Synonyms:

Chemical Property of (-)-((R,R)-2-exo-3-endo-bis(diphenylphosphino)bicyclo[2.2.1]heptene)(norbornadiene)rhodium perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (-)-((R,R)-2-exo-3-endo-bis(diphenylphosphino)bicyclo[2.2.1]heptene)(norbornadiene)rhodium perchlorate

There total 2 articles about (-)-((R,R)-2-exo-3-endo-bis(diphenylphosphino)bicyclo[2.2.1]heptene)(norbornadiene)rhodium perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

[(norbornadiene)rhodium(I)chloride]2 (12257-42-0) + (+)-(R,R)-Norphos + sodium perchlorate → (-)-((R,R)-2-exo-3-endo-bis(diphenylphosphino)bicyclo[2.2.1]heptene)(norbornadiene)rhodium perchlorate (78791-09-0)

Guidance literature:

In methanol; Rh complex and org. compd. stirred in MeOH under N2 for 1 h, aq. soln. of NaClO4 added portionwise over 2 h under stirring, mixture stirred for1 h; filtration, washing with H2O;

DOI:10.1021/ic50225a007

Reference yield: 64.0%

(bicyclo[2.2.1]hepta-2,5-diene)-(2,4-pentanedionato)rhodium (I) + (+)-(R,R)-Norphos → (-)-((R,R)-2-exo-3-endo-bis(diphenylphosphino)bicyclo[2.2.1]heptene)(norbornadiene)rhodium perchlorate (78791-09-0)

Guidance literature:

With HClO₄; In tetrahydrofuran; water; aq. HClO4 added to soln. of Rh complex and org. compd. in THF, mixture kept at room temp. for 48 h; filtration;

DOI:10.1021/ic50225a007

upstream raw materials:

[(norbornadiene)rhodium(I)chloride]2