(2R,4aS,6aS,8S,9aS,11S,13aS,14R,16aS,16bR)-methyl 11-acetoxy-8,14-dihydroxy-2,4a,6a,10,10,13a,16a-heptamethyl-7,15-dioxodocosahydro-8,14-epoxybenzo[6,7]cyclodeca[1,2-a]naphthalene-2-carboxylate

Base Information

Chemical Name:(2R,4aS,6aS,8S,9aS,11S,13aS,14R,16aS,16bR)-methyl 11-acetoxy-8,14-dihydroxy-2,4a,6a,10,10,13a,16a-heptamethyl-7,15-dioxodocosahydro-8,14-epoxybenzo[6,7]cyclodeca[1,2-a]naphthalene-2-carboxylate
CAS No.:1417814-25-5
Molecular Formula:C₃₃H₅₀O₉
Molecular Weight:590.755
Hs Code.:

(2R,4aS,6aS,8S,9aS,11S,13aS,14R,16aS,16bR)-methyl 11-acetoxy-8,14-dihydroxy-2,4a,6a,10,10,13a,16a-heptamethyl-7,15-dioxodocosahydro-8,14-epoxybenzo[6,7]cyclodeca[1,2-a]naphthalene-2-carboxylate

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Chemical Property of (2R,4aS,6aS,8S,9aS,11S,13aS,14R,16aS,16bR)-methyl 11-acetoxy-8,14-dihydroxy-2,4a,6a,10,10,13a,16a-heptamethyl-7,15-dioxodocosahydro-8,14-epoxybenzo[6,7]cyclodeca[1,2-a]naphthalene-2-carboxylate

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Technology Process of (2R,4aS,6aS,8S,9aS,11S,13aS,14R,16aS,16bR)-methyl 11-acetoxy-8,14-dihydroxy-2,4a,6a,10,10,13a,16a-heptamethyl-7,15-dioxodocosahydro-8,14-epoxybenzo[6,7]cyclodeca[1,2-a]naphthalene-2-carboxylate

There total 1 articles about (2R,4aS,6aS,8S,9aS,11S,13aS,14R,16aS,16bR)-methyl 11-acetoxy-8,14-dihydroxy-2,4a,6a,10,10,13a,16a-heptamethyl-7,15-dioxodocosahydro-8,14-epoxybenzo[6,7]cyclodeca[1,2-a]naphthalene-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 18.0%

: 1417814-14-2
(2R,4aS,6aS,8aR,10S,12aS,14aS,14bR)-methyl 10-acetoxy-2,4a,6a,9,9,12a,14a-heptamethyl-7,13-dioxo-1,2,3,4,4a,5,6,6a,7,8,8a,9,10,11,12,12a,13,14,14a,14b-icosahydropicene-2-carboxylate

: 1417814-22-2
(2R,4aS,6aS,9aS,11S,13aS,16aS,16bR)-methyl 11-acetoxy-2,4a,6a,10,10,13a,16a-heptamethyl-7,8,14,15-tetraoxodocosahydrobenzo[6,7]cyclodeca[1,2-a]naphthalene-2-carboxylate

: 1417814-23-3
(1S,2S,4aR,7R,8aR)-1-(3-((1S,2S,4S)-4-acetoxy-2-(carboxymethyl)-1,3,3-trimethylcyclohexyl)-2,3-dioxopropyl)-7-(methoxycarbonyl)-1,2,4a,7-tetramethyldecahydronaphthalene-2-carboxylic acid

: 1417814-25-5
(2R,4aS,6aS,8S,9aS,11S,13aS,14R,16aS,16bR)-methyl 11-acetoxy-8,14-dihydroxy-2,4a,6a,10,10,13a,16a-heptamethyl-7,15-dioxodocosahydro-8,14-epoxybenzo[6,7]cyclodeca[1,2-a]naphthalene-2-carboxylate

Guidance literature:: With ruthenium trichloride; sodium periodate; In tetrachloromethane; water; acetonitrile; at 20 ℃;
DOI:10.1021/jo302211f