Ti(OC₆H₄F)((C₆H₁₁)7Si₇O₁₂)

Base Information

• Chemical Name: Ti(OC₆H₄F)((C₆H₁₁)7Si₇O₁₂)
• CAS No.: 255839-50-0
• Molecular Formula: C₄₈H₈₁FO₁₃Si₇Ti
• Molecular Weight: 1129.64
• Mol file: 255839-50-0.mol

Synonyms:

Chemical Property of Ti(OC₆H₄F)((C₆H₁₁)7Si₇O₁₂)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ti(OC₆H₄F)((C₆H₁₁)7Si₇O₁₂)

There total 3 articles about Ti(OC₆H₄F)((C₆H₁₁)7Si₇O₁₂) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

4-Fluorophenol (371-41-5) + titanium isopropoxide cyclohexylsilsesquioxane (193273-96-0) → Ti(OC6H4F)((C6H11)7Si7O12) (255839-50-0)

Guidance literature:

In diethyl ether; byproducts: i-PrOH; (argon); dropwise addn. of 4-fluorophenol in Et2O to a stirred soln. of the Ti compd. in Et2O over 30 min, further stirring (room temp., 1 h); redn. of volume (vac.), pptn. on addn. of MeCN, filtration, washing (MeCN), drying (vac.); elem. anal.;

DOI:10.1039/a905887g

Reference yield:

1,3,5,7,9,11,14-heptacyclohexyltricyclo[7.3.3.1(5,11)]heptasiloxaneendo-3,7,14-triol (188612-43-3,47904-22-3,4115-83-7) → Ti(OC6H4F)((C6H11)7Si7O12) (255839-50-0)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: diethyl ether

In diethyl ether; toluene;

DOI:10.1039/a905887g

Reference yield:

4-Fluorophenol (371-41-5) + titanium isopropoxide cyclohexylsilsesquioxane (193273-96-0) → Ti(OC6H4F)((C6H11)7Si7O12) (255839-50-0) + (Ti((C6H11)7Si7O12))2(OC6H4F)2*2C4H8O

Guidance literature:

In tetrahydrofuran; (argon); dropwise addn. of 4-fluorophenol in THF to a stirred soln. of the Ti compd. in THF over 30 min, further stirring (room temp., 1 h); not separated (NMR monitoring);

DOI:10.1039/a905887g

upstream raw materials:

4-Fluorophenol

titanium isopropoxide cyclohexylsilsesquioxane

1,3,5,7,9,11,14-heptacyclohexyltricyclo[7.3.3.1(5,11)]heptasiloxaneendo-3,7,14-triol