2-chloro-4-ferrocenylbenzoic acid

Base Information

Chemical Name:2-chloro-4-ferrocenylbenzoic acid
CAS No.:516479-55-3
Molecular Formula:C₁₇H₁₃ClFeO₂
Molecular Weight:340.589
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-chloro-4-ferrocenylbenzoic acid

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Technology Process of 2-chloro-4-ferrocenylbenzoic acid

There total 1 articles about 2-chloro-4-ferrocenylbenzoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.0%

: 102-54-5,55404-68-7
ferrocene

: 2457-76-3
4-amino-2-chlorobenzoic acid

: 516479-55-3
2-chloro-4-ferrocenylbenzoic acid

Guidance literature:: With NaNO₂; In not given; under N2; diazonium method; substituted benzoic acid, ferrocene and NaNO2 (molar ratio 1:1:1.3) reacted; according to C. Imrie, C. Loubser, C. W. McCleland, P. Engelbrecht, J. Chem. Soc. Perkin Trans., 1 (1999) 2513; filtered; crystals recrystd. from hot C3H6O; elem. anal.;
DOI:10.1016/S0022-328X(02)02044-2

Reference yield: 49.0%

: 516479-55-3
2-chloro-4-ferrocenylbenzoic acid

: 91577-95-6
4-hydroxy-4'-decyloxybiphenyl

: 516479-82-6
4'-decyloxy-4-biphenyl-2-chloro-4-ferrocenylbenzoate

Guidance literature:: With 4-dimethylaminopyridine; dicyclohexylcarbodiimide; In dichloromethane; under N2; soln. of dicyclohexylcarbodiimide in anhyd. CH2Cl2 added over 1 min to soln. of biphenyl, Fe complex and 4-dimethylaminopyridine (molar ratio 3.8:3:3:1) in anhyd. CH2Cl2; stirred (room temp., 14 d); soln. filtered; solvent removed in vac.; purified by flash column chromy. (silica gel, C6H14-CH2Cl2); solvent removed from collected fractions; recrystd. from CH2Cl2-MeOH in the cold; elem. anal.;
DOI:10.1016/S0022-328X(02)02044-2

Reference yield: 45.0%

: 516479-55-3
2-chloro-4-ferrocenylbenzoic acid

: 78435-18-4
4-(4-octyloxyphenyl)phenol

: 516479-79-1
4'-octyloxy-4-biphenyl-2-chloro-4-ferrocenylbenzoate

Guidance literature:: With 4-dimethylaminopyridine; dicyclohexylcarbodiimide; In dichloromethane; under N2; soln. of dicyclohexylcarbodiimide in anhyd. CH2Cl2 added over 1 min to soln. of biphenyl, Fe complex and 4-dimethylaminopyridine (molar ratio 3.5:3:3:1) in anhyd. CH2Cl2; stirred (room temp., 14 d); soln. filtered; solvent removed in vac.; purified by flash column chromy. (silica gel, C6H14-CH2Cl2); solvent removed from collected fractions; recrystd. from CH2Cl2-MeOH; elem. anal.;
DOI:10.1016/S0022-328X(02)02044-2