benzyl(trifluoroacetato)(P(CH₃)(C₆H₅)2)2palladium(II)

Base Information

• Chemical Name: benzyl(trifluoroacetato)(P(CH₃)(C₆H₅)2)2palladium(II)
• CAS No.: 226703-30-6
• Molecular Formula: C₃₅H₃₃F₃O₂P₂Pd
• Molecular Weight: 711.009
• Mol file: 226703-30-6.mol

Synonyms:

Chemical Property of benzyl(trifluoroacetato)(P(CH₃)(C₆H₅)2)2palladium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzyl(trifluoroacetato)(P(CH₃)(C₆H₅)2)2palladium(II)

There total 2 articles about benzyl(trifluoroacetato)(P(CH₃)(C₆H₅)2)2palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + trans-PdEt2(PMePh2)2 + benzyl trifluoroacetate (351-70-2) → benzyl(trifluoroacetato)(P(CH3)(C6H5)2)2palladium(II) (688064-10-0,226895-08-5,226703-30-6)

Guidance literature:

In acetone; trans-Pd(CH2CH3)2(P(CH3)(C6H5)2)2 and styrene added to acetone at -20°C; standing the mixture at 50°C for 2 h; after cooling at room temp., benzyl trifluoroacetate added to this soln. and stirred at room temp. for 3 h; mixture concentrated; hexane added to precipitate the product; product filtrated and collected; washing with hexane and drying in cacuo;

DOI:10.1246/cl.2004.348

Reference yield: 79.0%

Pd(C2H5)2(CH3P(C6H5)2)2 (75172-21-3,60876-08-6,132957-78-9) + benzyl trifluoroacetate (351-70-2) → benzyl(trifluoroacetato)(P(CH3)(C6H5)2)2palladium(II) (688064-10-0,226895-08-5,226703-30-6)

Guidance literature:

DOI:10.1246/bcsj.72.799

upstream raw materials:

Pd(C₂H₅)2(CH₃P(C₆H₅)2)2

benzyl trifluoroacetate

styrene