tert-butyl{5-[2-(2-{[tert-butyl(dimethyl)silyl]oxy}-3,4-dimethoxyphenyl)ethenyl]-2-methoxyphenoxy}dimethylsilane

Base Information

• Chemical Name: tert-butyl{5-[2-(2-{[tert-butyl(dimethyl)silyl]oxy}-3,4-dimethoxyphenyl)ethenyl]-2-methoxyphenoxy}dimethylsilane
• CAS No.: 5259-66-5
• Molecular Formula: C9H14 O
• Molecular Weight: 138.21
• Mol file: 5259-66-5.mol

Synonyms:3-Cyclohexen-1-one,4-isopropyl- (7CI,8CI); 4-Isopropyl-3-cyclohexen-1-one

Chemical Property of tert-butyl{5-[2-(2-{[tert-butyl(dimethyl)silyl]oxy}-3,4-dimethoxyphenyl)ethenyl]-2-methoxyphenoxy}dimethylsilane

Chemical Property:

• Vapor Pressure: 1.12E-11mmHg at 25°C
• Boiling Point: 552.3°Cat760mmHg
• Flash Point: 236.1°C
• Density: 1.002g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tert-butyl{5-[2-(2-{[tert-butyl(dimethyl)silyl]oxy}-3,4-dimethoxyphenyl)ethenyl]-2-methoxyphenoxy}dimethylsilane

There total 17 articles about tert-butyl{5-[2-(2-{[tert-butyl(dimethyl)silyl]oxy}-3,4-dimethoxyphenyl)ethenyl]-2-methoxyphenoxy}dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

1-methoxy-4-(1'-methylethyl)cyclohexa-1,4-diene (99180-72-0) → isopropyl-4 cyclohexene-3 one-1 (5259-66-5)

Guidance literature:

With water; oxalic acid; In methanol; at 20 ℃; for 0.666667h;

DOI:10.1016/j.tetasy.2006.07.030

Reference yield:

(1R,5S)-(+)-nopinone (38651-65-9) → isopropyl-4 cyclohexene-3 one-1 (5259-66-5) + cryptone (2158-59-0,2158-61-4,100295-52-1,500-02-7)

Guidance literature:

With aluminium trichloride; In dichloromethane; at 0 - 5 ℃; for 1.16667h; Title compound not separated from byproducts;

DOI:10.1016/j.tetasy.2006.07.030

Reference yield:

2,4,6-trimethyl-pyridine (108-75-8) → isopropyl-4 cyclohexene-3 one-1 (5259-66-5) + cryptone (2158-59-0,2158-61-4,100295-52-1,500-02-7)

Guidance literature:

DOI:10.1021/ja01609a060

upstream raw materials:

2,4,6-trimethyl-pyridine

cryptone

2,4,6-trimethylpyridine hydrobromide

1-methoxy-4-(1-methylethyl)benzene

Downstream raw materials:

(+/-)-4-isopropyl-1-methyl-3-cyclohexen-1-ol

cryptone

4-isopropyl-cyclohex-3-enone-(2,4-dinitro-phenylhydrazone)

beta-terpinene