[Lu(η5-C5Me4CH2SiMe2NPh-κN)(CH2SiMe3)(THF)2]

Base Information

• Chemical Name: [Lu(η5-C5Me4CH2SiMe2NPh-κN)(CH2SiMe3)(THF)2]
• CAS No.: 915695-53-3
• Molecular Formula: C₃₀H₅₂LuNO₂Si₂
• Molecular Weight: 689.886
• Mol file: 915695-53-3.mol

Synonyms:

Chemical Property of [Lu(η5-C5Me4CH2SiMe2NPh-κN)(CH2SiMe3)(THF)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Lu(η5-C5Me4CH2SiMe2NPh-κN)(CH2SiMe3)(THF)2]

There total 2 articles about [Lu(η5-C5Me4CH2SiMe2NPh-κN)(CH2SiMe3)(THF)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + Lu(trimethylsilylmethyl)3(tetrahydrofuran)2 + HC5Me4CH2SiMe2NHPh (1158840-20-0) → [Lu(η5-C5Me4CH2SiMe2NPh-κN)(CH2SiMe3)(THF)2] (915695-53-3)

Guidance literature:

In pentane; byproducts: SiMe4; Ar; pentane suspn. of metal compd. treated with pentane soln. of ligand (1:1 molar ratio) at -78°C, stirred for 30 min, warmed to 0°C; pptd., filtered off, dried (vac.), elem. anal.;

DOI:10.1002/ejic.200800216

Reference yield:

Lu(trimethylsilylmethyl)3(tetrahydrofuran)2 + C5H(CH3)4CH2Si(CH3)2NHC6H5 → [Lu(η5-C5Me4CH2SiMe2NPh-κN)(CH2SiMe3)(THF)2] (915695-53-3)

Guidance literature:

In pentane; (under Ar, Schlenk); pentane soln. of ligand added to pentane soln. of Lu-complex at -78°C, stirred for 1 h, slowly warmed to 0°C,stirred for 2.5 h; filtered or solvent reduced, allowed to stand at -32°C overnight;

DOI:10.1016/j.jorganchem.2006.01.060

upstream raw materials:

tetrahydrofuran

HC₅Me₄CH₂SiMe₂NHPh