fac-Mo(CO)3(py)3

Base Information

• Chemical Name: fac-Mo(CO)3(py)3
• CAS No.: 66701-87-9
• Molecular Formula: C₁₈H₁₅MoN₃O₃
• Molecular Weight: 417.275
• Mol file: 66701-87-9.mol

Synonyms:

Chemical Property of fac-Mo(CO)3(py)3

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of fac-Mo(CO)3(py)3

There total 3 articles about fac-Mo(CO)3(py)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[HMo(CO)3(η5-pentamethylcyclopentadienyl)] → tricarbonyltris(pyridine)molybdenum (66701-87-9,15279-79-5) + 1,2,3,4,5-pentamethylcyclopentadiene (4045-44-7)

Guidance literature:

With C₅H₅N; In pyridine; (Ar); mixt. of Mo complex and pyridine was heated at 50°C for 30min;

DOI:10.1016/0022-328X(85)87194-1

Reference yield:

[Mo(pyridine)(CO)5] (14324-76-6) → tricarbonyltris(pyridine)molybdenum (66701-87-9,15279-79-5) + Mo(CO)4(py)2 (33570-29-5,16742-99-7) + molybdenum hexacarbonyl (13939-06-5,199620-15-0)

Guidance literature:

In solid; byproducts: CO, pyridine; heating (flowing dry N2, electric tube furnace, 1 h, 125°C); formation of Mo(CO) or other unstable species on further heating;

DOI:10.1007/BF01913379

Reference yield:

2Mo(2+)*4I(1-)*8CO=Mo2I4(CO)8 (22547-54-2) → fac-Mo(CO)3(py)3 (15279-79-5,66701-87-9) + mer-[MoI3(pyridine)3] (104010-55-1,15711-07-6)

Guidance literature:

With C₅H₅N; In pyridine; byproducts: CO; treatment of Mo-complex with pyridine at room temp. under Ar, refluxingovernight; cooling to -20°c, filtn. of yellow-orange solid, washing (toluene), drying, elem. anal.;

upstream raw materials:

[Mo(pyridine)(CO)5]

2Mo⁽²⁺⁾*4I^(1-)*8CO=Mo₂I₄(CO)8

Downstream raw materials:

tricarbonyl[dimethyl(η6-phenyl)phenylethynylsilane]-molybdenum(0)

[Mo(CO)₃(dppe)(py)]