[(4-chlorobutyl)diphenylphosphane]-(η5-cyclopentadienyl)iodonickel

Base Information

Chemical Name:[(4-chlorobutyl)diphenylphosphane]-(η5-cyclopentadienyl)iodonickel
CAS No.:84516-86-9
Molecular Formula:C₂₁H₂₃ClINiP
Molecular Weight:527.435
Hs Code.:

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Chemical Property of [(4-chlorobutyl)diphenylphosphane]-(η5-cyclopentadienyl)iodonickel

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Technology Process of [(4-chlorobutyl)diphenylphosphane]-(η5-cyclopentadienyl)iodonickel

There total 1 articles about [(4-chlorobutyl)diphenylphosphane]-(η5-cyclopentadienyl)iodonickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

: [Ni(cyclopentadienyl)(μ-CO)]2

: 79369-66-7
(4-chlorobutyl)diphenylphosphine

: 84516-86-9
[(4-chlorobutyl)diphenylphosphane]-(η5-cyclopentadienyl)iodonickel

Guidance literature:: With I₂; In dichloromethane; byproducts: CO; under N2; to a solution of the Ni-complex was dropped an equimolar amount I2 during 1 h at -20°C; after 15 min the organic ligand (in CH2Cl2) was added; warmed to 20°C; solvent was removed in vacuo; chromatographed (Kieselgel, eluent-toluene); elem. anal.;

Reference yield: 23.0%

: 84516-86-9
[(4-chlorobutyl)diphenylphosphane]-(η5-cyclopentadienyl)iodonickel

: 2.2-(η5-cyclopentadienyl)-1.1-diphenyl-1-phospha-2-nickelacyclohexane

Guidance literature:: With Na/Hg; In tetrahydrofuran; under N2; to an excess of 1% Na/Hg was added at room temperature a solution of the Ni-complex; 5 h; decanted; solvent was removed in vacuo; residue was extracted with hexane; chromatographed (Kieselgel, eluent-n-hexane/ether 1:1); elem. anal.;