[(2,6-bis(di-tert-butyl phosphino methyl)pyridine)Rh(PPh₃)]BF₄

Base Information

• Chemical Name: [(2,6-bis(di-tert-butyl phosphino methyl)pyridine)Rh(PPh₃)]BF₄
• CAS No.: 1048014-86-3
• Molecular Formula: BF₄*C₄₁H₅₈NP₃Rh
• Molecular Weight: 847.55
• Mol file: 1048014-86-3.mol

Synonyms:

Chemical Property of [(2,6-bis(di-tert-butyl phosphino methyl)pyridine)Rh(PPh₃)]BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(2,6-bis(di-tert-butyl phosphino methyl)pyridine)Rh(PPh₃)]BF₄

There total 3 articles about [(2,6-bis(di-tert-butyl phosphino methyl)pyridine)Rh(PPh₃)]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[(2,6-bis(di-tert-butyl phosphino methyl)pyridine)Rh(acetone)][BF4]2 + water (7732-18-5) + triphenylphosphine (603-35-0) → [(2,6-bis(di-tert-butyl phosphino methyl)pyridine)Rh(PPh3)]BF4 (1048014-86-3)

Guidance literature:

In acetone; (N2); std. Schlenk technique; Ph3P (1.5 equiv.) and drop of H2O were added to soln. of Rh complex in acetone; mixt. was stirred at ambient temp.for 2 d; solvent removed (vac.); elem. anal.;

DOI:10.1021/ic701044b

Reference yield:

2,6-bis((di-tertbutylphosphino)methyl)pyridine → [(2,6-bis(di-tert-butyl phosphino methyl)pyridine)Rh(PPh3)]BF4 (1048014-86-3)

Guidance literature:

Multi-step reaction with 2 steps

1: acetone

2: acetone

In acetone;

DOI:10.1021/ic701044b

Reference yield:

[(2,6-bis(di-tert-butyl phosphino methyl)pyridine)Rh(acetone)]BF4 (1048014-73-8) + triphenylphosphine (603-35-0) → [(2,6-bis(di-tert-butyl phosphino methyl)pyridine)Rh(PPh3)]BF4 (1048014-86-3)

Guidance literature:

In acetone; (N2); std. Schlenk technique; soln. of Rh complex and Ph3P in acetone was heated at 50°C for 4 h;

DOI:10.1021/ic701044b

upstream raw materials:

water

triphenylphosphine

[(2,6-bis(di-tert-butyl phosphino methyl)pyridine)Rh(acetone)]BF₄