Ru(CHCHCH₂OSi(CH₃)2C(CH₃)3)Cl(CO)(P(C₆H₅)3)2

Base Information

• Chemical Name: Ru(CHCHCH₂OSi(CH₃)2C(CH₃)3)Cl(CO)(P(C₆H₅)3)2
• CAS No.: 1092555-80-0
• Molecular Formula: C₄₆H₄₉ClO₂P₂RuSi
• Molecular Weight: 860.45
• Mol file: 1092555-80-0.mol

Synonyms:

Chemical Property of Ru(CHCHCH₂OSi(CH₃)2C(CH₃)3)Cl(CO)(P(C₆H₅)3)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Ru(CHCHCH₂OSi(CH₃)2C(CH₃)3)Cl(CO)(P(C₆H₅)3)2

There total 1 articles about Ru(CHCHCH₂OSi(CH₃)2C(CH₃)3)Cl(CO)(P(C₆H₅)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) (157072-60-1,61521-25-3,166941-05-5,16971-33-8) + tert-Butyldimethyl(prop-2-ynyloxy)silane (76782-82-6) → Ru(CHCHCH2OSi(CH3)2C(CH3)3)Cl(CO)(P(C6H5)3)2 (1092555-80-0)

Guidance literature:

In dichloromethane; Ru complex dissolved in CH2Cl2; HCCCH2OSiMe2-t-Bu added; stirred at roomtemp. for 1 h; EtOH added; concd. slowly under reduced pressure; filtered; ppt. washed with EtOH and hexane; dried under vac.; elem. anal.;

DOI:10.1021/om800686f

Reference yield: 60.0%

carbon disulfide (75-15-0,12122-00-8) + Ru(CHCHCH2OSi(CH3)2C(CH3)3)Cl(CO)(P(C6H5)3)2 (1092555-80-0) + [Ru(C(CCPh)=CHPh)(CO)(PPh3)2(piperazine dithiocarbamate)]Cl (1092555-74-2) → Ru(C(C2C6H5)CHC6H5)(CO)(P(C6H5)3)2(S2CNC4H8NCS2)Ru(CHCHCH2OSi(CH3)2C(CH3)3)(CO)(P(C6H5)3)2

Guidance literature:

With Et₃N; In dichloromethane; soln. of cationic Ru complex in CH2Cl2 treated with Et3N (excess) and CS2 (excess); stirred for 5 min; another Ru complex in CH2Cl2 added; stirred for 15 min; filtered (diatomaceous earth); EtOH added; concd. under reduced pressure; filtered; ppt. washed with hexane; dried under vac.; elem. anal.;

DOI:10.1021/om800686f

upstream raw materials:

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

tert-Butyldimethyl(prop-2-ynyloxy)silane