Ni(2,3,12,13-tetrabromo-7,8,17,18-tetramethyl-5,10,15,20-tetraphenylporphyrin^(2-))

Base Information

• Chemical Name: Ni(2,3,12,13-tetrabromo-7,8,17,18-tetramethyl-5,10,15,20-tetraphenylporphyrin^(2-))
• CAS No.: 889678-09-5
• Molecular Formula: C₄₈H₃₂Br₄N₄Ni
• Molecular Weight: 1043.11
• Mol file: 889678-09-5.mol

Synonyms:

Chemical Property of Ni(2,3,12,13-tetrabromo-7,8,17,18-tetramethyl-5,10,15,20-tetraphenylporphyrin^(2-))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ni(2,3,12,13-tetrabromo-7,8,17,18-tetramethyl-5,10,15,20-tetraphenylporphyrin^(2-))

There total 1 articles about Ni(2,3,12,13-tetrabromo-7,8,17,18-tetramethyl-5,10,15,20-tetraphenylporphyrin^(2-)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

N-Bromosuccinimide (128-08-5) + Ni(2,3,12,13-tetramethyl-5,10,15,20-tetraphenylporphyrin(2-)) (889678-03-9) → Ni(2,3,12,13-tetrabromo-7,8,17,18-tetramethyl-5,10,15,20-tetraphenylporphyrin(2-)) (889678-09-5)

Guidance literature:

In chloroform; to soln. Ni complex in CHCl3 NBS was added and refluxed for 4 h; soln. was cooled to room temp., solvent was removed in vacuo, residue was washed with MeOH and chromed. on silica (CHCl3), product was dried for6 h under vac. (3 mbar) at 100°C; elem. anal.;

DOI:10.1021/ic052035b

Reference yield: 40.0%

Ni(2,3,12,13-tetrabromo-7,8,17,18-tetramethyl-5,10,15,20-tetraphenylporphyrin(2-)) (889678-09-5) + copper(l) cyanide → Ni(2,3,12-tricyano-7,8,17,18-tetramethyl-5,10,15,20-tetraphenylporphyrin(2-)) (1016971-22-4) + Ni(2,3,12,13-tetracyano-7,8,17,18-tetramethyl-5,10,15,20-tetraphenylporphyrin(2-)) (889678-13-1)

Guidance literature:

In pyridine; to soln. Ni complex in pyridine CuCN was added and refluxed for 48 h under Ar atm.; solvent was evapd. in vacuo, residue was dissolved in CHCl3 and chromed.on silica (CHCl3); elem. anal.;

DOI:10.1021/ic052035b

upstream raw materials:

N-Bromosuccinimide

Ni(2,3,12,13-tetramethyl-5,10,15,20-tetraphenylporphyrin^(2-))

Downstream raw materials:

Ni(2,3,12-tricyano-7,8,17,18-tetramethyl-5,10,15,20-tetraphenylporphyrin^(2-))

Ni(2,3,12,13-tetracyano-7,8,17,18-tetramethyl-5,10,15,20-tetraphenylporphyrin^(2-))