tetracarbonyl(tribenzylstannanedithiocarboxylato-S,S)rhenium(I)

Base Information

Chemical Name:tetracarbonyl(tribenzylstannanedithiocarboxylato-S,S)rhenium(I)
CAS No.:87097-46-9
Molecular Formula:C₂₆H₂₁O₄ReS₂Sn
Molecular Weight:766.499
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tetracarbonyl(tribenzylstannanedithiocarboxylato-S,S)rhenium(I)

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Technology Process of tetracarbonyl(tribenzylstannanedithiocarboxylato-S,S)rhenium(I)

There total 1 articles about tetracarbonyl(tribenzylstannanedithiocarboxylato-S,S)rhenium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 18.0%

: 75-15-0,12122-00-8
carbon disulfide

: 14220-21-4
rhenium(I) pentacarbonyl bromide

: 3151-41-5
tribenzyltin(IV) chloride

: 87097-46-9
tetracarbonyl(tribenzylstannanedithiocarboxylato-S,S)rhenium(I)

Guidance literature:: With lithium; In tetrahydrofuran; 1,4-dioxane; byproducts: CO, LiBr; stirring a mixt. of Bz3SnCl and activated Li in THF (N2) for 1-3 d, removal of excess Li and addn. of CS2 dissolved in dioxane, evapn. of THF, sepn. of the residue, washing with dioxane four times and addn. of BrRe(CO)5 to the combined dioxane extracts; evapn. of the solvent after stirring at 60°C for 20-25 h, purificn. by column chromatography, eluating the first yellow fraction with n-hexane, recrystn. from n-hexane;