Rh(CO)(Cl)(((C₆H₅)2P)2CHC₅H₄N)

Base Information

• Chemical Name: Rh(CO)(Cl)(((C₆H₅)2P)2CHC₅H₄N)
• CAS No.: 86943-74-0
• Molecular Formula: C₃₁H₂₅ClNOP₂Rh
• Molecular Weight: 627.852

Synonyms:

Chemical Property of Rh(CO)(Cl)(((C₆H₅)2P)2CHC₅H₄N)

Chemical Property:

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Technology Process of Rh(CO)(Cl)(((C₆H₅)2P)2CHC₅H₄N)

There total 1 articles about Rh(CO)(Cl)(((C₆H₅)2P)2CHC₅H₄N) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

[Rh2(CO)2(((C6H5)2P)2CHC5H4N)2](2+)*2PF6(1-)*(CH3)2CO=[Rh2(CO)2(((C6H5)2P)2CHC5H4N)2](PF6)2*(CH3)2CO (86992-66-7) + tetraethylammonium chloride monohydrate (68696-18-4) → Rh(CO)(Cl)(((C6H5)2P)2CHC5H4N) (86943-74-0)

Guidance literature:

In acetone; under N2, Rh complex disoolved in dry acetone, satd. acetone soln. of NEt4Cl*H2O added dropwise; dried over anhyd. Na2SO4 for 1 h, filtered, cooled to -78°C, layered with hexane, allowed to stand at room temp. for 24 h, solvents syringed off, solids dried in stream of N2, crystals sepd. manually; elem. anal.;

Reference yield:

Rh(CO)(Cl)(((C6H5)2P)2CHC5H4N) (86943-74-0) → Rh2(S)(CO)2(((C6H5)2P)2CHC5H4N)2 (86943-73-9)

Guidance literature:

With Na₂S; In acetone; under N2, addn. of Na2S to acetone soln. of educt;

Reference yield:

Rh(CO)(Cl)(((C6H5)2P)2CHC5H4N) (86943-74-0) → [Rh2(CO)2(((C6H5)2P)2CHC5H4N)2](2+) (86992-66-7)

Guidance literature:

In water; acetone; under N2, addn. of water (only 5% by vol.) to acetone soln. of educt; detected spectroscopically;

upstream raw materials:

[Rh₂(CO)2(((C₆H₅)2P)2CHC₅H₄N)2]⁽²⁺⁾*2PF₆^(1-)*(CH₃)2CO=[Rh₂(CO)2(((C₆H₅)2P)2CHC₅H₄N)2](PF₆)2*(CH₃)2CO

tetraethylammonium chloride monohydrate

Downstream raw materials:

[Rh₂(CO)2(((C₆H₅)2P)2CHC₅H₄N)2]⁽²⁺⁾

Rh₂(S)(CO)2(((C₆H₅)2P)2CHC₅H₄N)2

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