Technology Process of 15,15-Bis(11,11,11-triphenylundecyl)-2,14,16,28-tetraoxatricyclo<27.2.2.013,17>tritriaconta-1(31),29,32-trien
There total 9 articles about 15,15-Bis(11,11,11-triphenylundecyl)-2,14,16,28-tetraoxatricyclo<27.2.2.013,17>tritriaconta-1(31),29,32-trien which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
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73819-07-5,73837-64-6
15,15-Bis(11,11,11-triphenylundecyl)-2,14,16,28-tetraoxatricyclo<27.2.2.013,17>tritriaconta-1(31),29,32-trien
- Guidance literature:
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Multi-step reaction with 5 steps
1: 70 percent / sodium methylate / methanol / 10 h / Heating
2: 78 percent / sodium sand / xylene / 2 h / 110 °C
3: 81 percent / lithium alanate / diethyl ether / 1 h / Heating
4: 59 percent / p-toluenesulfonic acid, Mg(ClO4)2 / benzene / 24 h / Heating
5: 1.) BuLi / 1.) ether, THF, 15 min, 0 deg C, 15 min, room temp., 2.) 2 h, room temp.
With
lithium aluminium tetrahydride; n-butyllithium; magnesium(II) perchlorate; sodium sand; sodium methylate; toluene-4-sulfonic acid;
In
methanol; diethyl ether; xylene; benzene;
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73819-07-5,73837-64-6
15,15-Bis(11,11,11-triphenylundecyl)-2,14,16,28-tetraoxatricyclo<27.2.2.013,17>tritriaconta-1(31),29,32-trien
- Guidance literature:
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Multi-step reaction with 2 steps
1: 59 percent / p-toluenesulfonic acid, Mg(ClO4)2 / benzene / 24 h / Heating
2: 1.) BuLi / 1.) ether, THF, 15 min, 0 deg C, 15 min, room temp., 2.) 2 h, room temp.
With
n-butyllithium; magnesium(II) perchlorate; toluene-4-sulfonic acid;
In
benzene;
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73819-07-5,73837-64-6
15,15-Bis(11,11,11-triphenylundecyl)-2,14,16,28-tetraoxatricyclo<27.2.2.013,17>tritriaconta-1(31),29,32-trien
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 81 percent / lithium alanate / diethyl ether / 1 h / Heating
2: 59 percent / p-toluenesulfonic acid, Mg(ClO4)2 / benzene / 24 h / Heating
3: 1.) BuLi / 1.) ether, THF, 15 min, 0 deg C, 15 min, room temp., 2.) 2 h, room temp.
With
lithium aluminium tetrahydride; n-butyllithium; magnesium(II) perchlorate; toluene-4-sulfonic acid;
In
diethyl ether; benzene;
