6-t-butyl-1,2,3-tris-(4-t-butylphenyl)azulene radical cation

Base Information

• Chemical Name: 6-t-butyl-1,2,3-tris-(4-t-butylphenyl)azulene radical cation
• CAS No.: 117953-25-0
• Molecular Formula: C₄₄H₅₂
• Molecular Weight: 580.897
• Mol file: 117953-25-0.mol

Synonyms:

Chemical Property of 6-t-butyl-1,2,3-tris-(4-t-butylphenyl)azulene radical cation

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6-t-butyl-1,2,3-tris-(4-t-butylphenyl)azulene radical cation

There total 6 articles about 6-t-butyl-1,2,3-tris-(4-t-butylphenyl)azulene radical cation which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

bis(4-tert-butylphenyl)acetylene (61440-86-6) → 6-t-butyl-1,2,3-tris-(4-t-butylphenyl)azulene (117953-25-0)

Guidance literature:

With mercury(II) trifluoroacetate; In trifluoroacetic acid;

Reference yield:

bis(4-tert-butylphenyl)acetylene (61440-86-6) → 6-t-butyl-1,2,3-tris-(4-t-butylphenyl)azulene radical cation (117953-25-0)

Guidance literature:

Multi-step reaction with 2 steps

1: Hg(CF₃COO)2 / trifluoroacetic acid / Irradiation

2: trifluoroacetic acid / Irradiation

With Hg(II) trifluoroacetate; In trifluoroacetic acid;

DOI:10.1039/c39860000549

Reference yield:

4-tert-butyltoluene (98-51-1) → 6-t-butyl-1,2,3-tris-(4-t-butylphenyl)azulene (117953-25-0)

Guidance literature:

Multi-step reaction with 4 steps

1: bromine / Irradiation

2: copper / toluene

3: potassium hydroxide / dioxane / Heating

4: 43 percent / mercury(II)trifluoroaceate / trifluoroacetic acid

With potassium hydroxide; bromine; mercury(II) trifluoroacetate; copper; In 1,4-dioxane; toluene; trifluoroacetic acid;

upstream raw materials:

bis(4-tert-butylphenyl)acetylene

4-tert-butyltoluene

p-tert-butyl-α,α-dibromotoluene

1,2-Dibromo-1,2-bis(p-tert-butylphenyl)ethane