RhCl(CO)(tricyclohexylphosphine)2

Base Information

Chemical Name:RhCl(CO)(tricyclohexylphosphine)2
CAS No.:17966-79-9
Molecular Formula:C₃₇H₆₆ClOP₂Rh
Molecular Weight:727.236
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of RhCl(CO)(tricyclohexylphosphine)2

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Technology Process of RhCl(CO)(tricyclohexylphosphine)2

There total 14 articles about RhCl(CO)(tricyclohexylphosphine)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: di(rhodium)tetracarbonyl dichloride

: 2622-14-2
tricyclohexylphosphine

: 17966-79-9,26534-14-5
trans-((C₆H₁₁)3P)2Rh(CO)Cl

Guidance literature:: In benzene; N2 atmosphere, 2% excess PCy3; concn., pptn. (addn. of EtOH), filtn., washing (ethanol/ether 1:1);

Reference yield: 85.0%

: di-μ-chloro-bis[bis(cyclo-octene)rhodium]

: 2622-14-2
tricyclohexylphosphine

: 17966-79-9,26534-14-5
trans-((C₆H₁₁)3P)2Rh(CO)Cl

Guidance literature:: With CO; In light petroleum; stirring Rh-complex with organic compound in light petroleum under argon for 20 h, removing solvent in vac., dissolving product in Et2O, bubbling CO through the soln. for 5 min; concg., holding at -30°C for 18 h, filtn., washing (cold Et2O) at -50°C, drying in vac.;
DOI:10.1039/DT9940001963

Reference yield: 78.0%

: 494804-05-6
dodecacarbonyltetrarhodium⁽⁰⁾

: 2622-14-2
tricyclohexylphosphine

: 17966-79-9,26534-14-5
trans-((C₆H₁₁)3P)2Rh(CO)Cl

Guidance literature:: With hydrogenchloride; In further solvent(s); under N2, to soln. of Rh4(CO)12 and P(C6H11)3 in tetramethylurea HCl (36%) added, mixed for 5 h at room temp.; evapd., recrystd. from toluene; elem. anal.;
DOI:10.1039/DT9870002969