hydridotricarbonylbis(tri-ortho-tolylphosphite)manganese

Base Information

Chemical Name:hydridotricarbonylbis(tri-ortho-tolylphosphite)manganese
CAS No.:84180-15-4
Molecular Formula:C₄₅H₄₃MnO₉P₂
Molecular Weight:844.717
Hs Code.:

Synonyms:

Suppliers and Price of hydridotricarbonylbis(tri-ortho-tolylphosphite)manganese

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 2 raw suppliers

Chemical Property of hydridotricarbonylbis(tri-ortho-tolylphosphite)manganese

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of hydridotricarbonylbis(tri-ortho-tolylphosphite)manganese

There total 2 articles about hydridotricarbonylbis(tri-ortho-tolylphosphite)manganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 113626-72-5,90423-24-8
bromotricarbonylbis(tri-ortho-tolylphosphite)manganese

: 84180-15-4,90458-73-4
hydridotricarbonylbis(tri-ortho-tolylphosphite)manganese

Guidance literature:: With sodium amalgam; acetic acid; In tetrahydrofuran; byproducts: NaBr, CH3CO2Na; shaking Mn complex with sodium amalgam (excess) under N2, 2 h; separating Hg; addn. of equimolar amt. of acetic acid, -80°C; warm up to room temp., filtn., removal of solvent, chromy. (silica gel, petroleum ether/ether); elem. anal.;

Reference yield:

: 114129-97-4
tetra-n-butylammonium bis(tri-o-tolylphosphite)tricarbonylmanganate

: 688-73-3
tri-n-butyl-tin hydride

: 113821-92-4
Mn(CO)3{P(CH₃C₆H₄O)3}2((C₄H₉)3Sn)

: 84180-15-4
HMn(CO)3{P(CH₃C₆H₄O)3}2

Guidance literature:: In tetrahydrofuran; byproducts: (C4H9)3SnSn(C4H9)3; Electrochem. Process; electrooxidn. at > -0.59 V under Ar in 0.3 M (C4H9)4NClO4 at 22°C until the passage of current ceases; 70% hydrido-complex, 30% Sn-complex (IR);
DOI:10.1016/S0022-328X(00)99774-2

Reference yield:

: 84180-15-4,90458-73-4
hydridotricarbonylbis(tri-ortho-tolylphosphite)manganese

: 437-17-2
tritylium hexafluorophosphate

: 90422-52-9
tetracarbonylbis(tri-ortho-tolylphosphite)manganese(I) hexafluorophosphate

Guidance literature:: With carbon monoxide; In dichloromethane; byproducts: (C6H5)3CH; dissoln. of Mn complex in a minimum amt. of CH2Cl2; addn. of equimolar amt. of (C6H5)3CPF6, -80°C; heating to room temp. under CO (4 h); addn. of ether, filtn., recrystn. (THF/ether, -40°C); elem. anal.;