[RuH(CO)(triphenylphosphine)2(pyridine-2-carbaldehyde azine)](PF₆)

Base Information

• Chemical Name: [RuH(CO)(triphenylphosphine)2(pyridine-2-carbaldehyde azine)](PF₆)
• CAS No.: 730958-02-8
• Molecular Formula: C₄₉H₄₁N₄OP₂Ru*F₆P
• Molecular Weight: 1009.87
• Mol file: 730958-02-8.mol

Synonyms:

Chemical Property of [RuH(CO)(triphenylphosphine)2(pyridine-2-carbaldehyde azine)](PF₆)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [RuH(CO)(triphenylphosphine)2(pyridine-2-carbaldehyde azine)](PF₆)

There total 1 articles about [RuH(CO)(triphenylphosphine)2(pyridine-2-carbaldehyde azine)](PF₆) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

ammonium hexafluorophosphate + (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) (157072-60-1,61521-25-3,166941-05-5,16971-33-8) + 2-pyridinecarbaldehyde azine (6957-24-0) → [RuH(CO)(triphenylphosphine)2(pyridine-2-carbaldehyde azine)](PF6) (730958-02-8)

Guidance literature:

In methanol; (N2); treatment of suspn. of RuH(CO)(PPh3)3Cl (1 equiv.) in MeOH with pyridine-2-carbaldehyde azine (2 equiv.); reflux for 20 h; cooling to roomtemp., filtration, addn. of satd. soln. of NH4PF6 in MeOH to filtrate; concn. using rotary evaporator; crystn. in refrigerator for a couple days; sepn. by filtration, washing with MeOH, Et2O, drying in vac., elem. anal.;

DOI:10.1016/j.jorganchem.2004.03.044

upstream raw materials:

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

2-pyridinecarbaldehyde azine