Technology Process of C26H46O3Si
There total 7 articles about C26H46O3Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
3-bromofurane;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at -78 ℃;
for 0.166667h;
C22H42O2Si;
In
tetrahydrofuran; hexane;
at -78 ℃;
DOI:10.1002/ejoc.200901021
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: oxalyl dichloride; dimethyl sulfoxide; triethylamine / dichloromethane / -60 °C / Inert atmosphere
2.1: n-butyllithium / tetrahydrofuran; hexane / 0.17 h / -78 °C
2.2: -78 °C
With
n-butyllithium; oxalyl dichloride; dimethyl sulfoxide; triethylamine;
In
tetrahydrofuran; hexane; dichloromethane;
1.1: Swern oxidation;
DOI:10.1002/ejoc.200901021
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: potassium tert-butylate / toluene / 0.75 h / 20 °C / Inert atmosphere; Cooling with ice
2.1: lithium aluminium tetrahydride
3.1: tert-butyldimethylsilyl chloride
4.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 3 h / 25 °C / Inert atmosphere
4.2: 1 h / 25 °C / Inert atmosphere
5.1: oxalyl dichloride; dimethyl sulfoxide; triethylamine / dichloromethane / -60 °C / Inert atmosphere
6.1: n-butyllithium / tetrahydrofuran; hexane / 0.17 h / -78 °C
6.2: -78 °C
With
lithium aluminium tetrahydride; n-butyllithium; oxalyl dichloride; potassium tert-butylate; tert-butyldimethylsilyl chloride; dimethyl sulfoxide; triethylamine; 9-bora-bicyclo[3.3.1]nonane;
In
tetrahydrofuran; hexane; dichloromethane; toluene;
1.1: Wittig reaction / 5.1: Swern oxidation;
DOI:10.1002/ejoc.200901021
