5-ruthenocenylbenzaldehyde

Base Information

Chemical Name:5-ruthenocenylbenzaldehyde
CAS No.:1007403-82-8
Molecular Formula:C₁₇H₁₄ORu
Molecular Weight:335.368
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 5-ruthenocenylbenzaldehyde

Chemical Property:

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Technology Process of 5-ruthenocenylbenzaldehyde

There total 1 articles about 5-ruthenocenylbenzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

: 473926-52-2
2-ruthenocenyl-4,4,5,5-tetramethyl-1,3-dioxa-2-borolane

: 1122-91-4
4-bromo-benzaldehyde

: 1007403-82-8
5-ruthenocenylbenzaldehyde

Guidance literature:: With sodium hydroxide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In 1,2-dimethoxyethane; water; (Ar); mixt. of aldehyde, Ru complex, Pd catalyst, CsCO3, aq. NaOH in DMEin sealed tube was heated at 70°C for 10 h; washed (CH2Cl2); washed (H2O); dried (MgSO4); evapd.; chromd. (SiO2, CH2Cl2); elem. anal.;
DOI:10.1016/j.jorganchem.2007.07.057

Reference yield:

: 1007403-82-8
5-ruthenocenylbenzaldehyde

: ruthenoceny(triphenyl)phosphonium bromide

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

: [4-(2'-ruthenocenyl-E-ethenyl)-1-ruthenocenylbenzene]*0.5C₆H₆

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; (Ar); soln. of amide in THF was added to suspn. of phosphonium salt in THF at -78°C; stirred for 30 min; soln. of Ru-S complex was added;gradually warmed to room remp.; stirred for 1 h; refluxed for 3 h; aq. NH4Cl added; extd. (CH2Cl2); extract washed (H2O); dried (MgSO4); evapd.; chromd. (SiO2, hexane/C6H6); fractionally recrystd. (C6H6); elem. anal.;
DOI:10.1016/j.jorganchem.2007.07.057