[Ir2(H)(CO)3(μ-difluorovinylidene)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]

Base Information

Chemical Name:[Ir2(H)(CO)3(μ-difluorovinylidene)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]
CAS No.:1357616-45-5
Molecular Formula:C₂₃H₄₅F₂Ir₂O₃P₄*C₃₂H₁₂BF₂₄
Molecular Weight:1779.16
Hs Code.:

Synonyms:

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Chemical Property of [Ir2(H)(CO)3(μ-difluorovinylidene)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]

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Technology Process of [Ir2(H)(CO)3(μ-difluorovinylidene)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]

There total 4 articles about [Ir2(H)(CO)3(μ-difluorovinylidene)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 1357616-33-1
[Ir2H(CO)2(μ-CO)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]

: 359-11-5
1,1,2-trifluoroethylene

: 1357616-45-5
[Ir2(H)(CO)3(μ-difluorovinylidene)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]

: [Ir2(H)(CO)3(μ-2,2,2-trifluoroethylidene)(difluorovinyl)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]

Guidance literature:: In dichloromethane-d2; (Ar); using Schlenk techniques; dissolving of Ir2(CO)3(H)(PEt2CH2PEt2)2B((CF3)2C6H3)4 in CD2Cl2, cooling to -80°C, addn. of CF2CHF, keeping at -30°C for 2 h, warming to -15°C, leaving at ambient temp. overnight; monitoring by NMR, transferring to Schlenk tube, removal of solvent under vac., redissolving in Et2O, addn. of pentane, pptn., washing with pentane, drying;
DOI:10.1021/om2011968

Reference yield:

: 1357616-33-1
[Ir2H(CO)2(μ-CO)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]

: 359-11-5
1,1,2-trifluoroethylene

: [Ir2(H)(CO)3(μ-2,2,2-trifluoroethylidene)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]

: 1357616-45-5
[Ir2(H)(CO)3(μ-difluorovinylidene)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]

Guidance literature:: With water; In dichloromethane-d2; (Ar); using Schlenk techniques; dissolving of Ir2(CO)3(H)(PEt2CH2PEt2)2B((CF3)2C6H3)4 in CD2Cl2, cooling to -80°C, addn. of CF2CHF, keeping at -30°C for 2 h, warming to -15°C for 1 h (in the presence of water); as mixt. in 1:1 ratio;
DOI:10.1021/om2011968

Reference yield:

: [Ir2H(CO)3(μ-trifluoroethylene)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]

: 1357616-45-5
[Ir2(H)(CO)3(μ-difluorovinylidene)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]

Guidance literature:: In water-d2; (Ar); using Schlenk techniques; treatment of (Ir2(CO)3(H)(CF2CHF)(PEt2CH2PEt2)2)B((CF3)2C6H3)4 with D2O at -20°C;
DOI:10.1021/om2011968