(5R,6S)-5-((2S)-4-((4S,5S)-5-(but-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-methylbutyl)-6,10,10-trimethyl-9,9-diphenyl-2,4,8-trioxa-9-silaundecane

Base Information

Chemical Name:(5R,6S)-5-((2S)-4-((4S,5S)-5-(but-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-methylbutyl)-6,10,10-trimethyl-9,9-diphenyl-2,4,8-trioxa-9-silaundecane
CAS No.:1429470-14-3
Molecular Formula:C₃₆H₅₆O₅Si
Molecular Weight:596.923
Hs Code.:

(5R,6S)-5-((2S)-4-((4S,5S)-5-(but-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-methylbutyl)-6,10,10-trimethyl-9,9-diphenyl-2,4,8-trioxa-9-silaundecane

Synonyms:

Suppliers and Price of (5R,6S)-5-((2S)-4-((4S,5S)-5-(but-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-methylbutyl)-6,10,10-trimethyl-9,9-diphenyl-2,4,8-trioxa-9-silaundecane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (5R,6S)-5-((2S)-4-((4S,5S)-5-(but-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-methylbutyl)-6,10,10-trimethyl-9,9-diphenyl-2,4,8-trioxa-9-silaundecane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (5R,6S)-5-((2S)-4-((4S,5S)-5-(but-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-methylbutyl)-6,10,10-trimethyl-9,9-diphenyl-2,4,8-trioxa-9-silaundecane

There total 13 articles about (5R,6S)-5-((2S)-4-((4S,5S)-5-(but-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-methylbutyl)-6,10,10-trimethyl-9,9-diphenyl-2,4,8-trioxa-9-silaundecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₃₅H₅₄O₆Si

: 2065-66-9
methyl-triphenylphosphonium iodide

: 1429470-14-3
(5R,6S)-5-((2S)-4-((4S,5S)-5-(but-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-methylbutyl)-6,10,10-trimethyl-9,9-diphenyl-2,4,8-trioxa-9-silaundecane

Guidance literature:: With potassium hexamethylsilazane; In tetrahydrofuran; at -78 - 20 ℃;
DOI:10.1016/j.tetlet.2013.02.052

Reference yield:

: 1429470-11-0
(2R,4R,5S)-6-(tert-butyldiphenylsilyloxy)-4-(methoxymethoxy)-2,5-dimethylhexan-1-ol

: 1429470-14-3
(5R,6S)-5-((2S)-4-((4S,5S)-5-(but-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-methylbutyl)-6,10,10-trimethyl-9,9-diphenyl-2,4,8-trioxa-9-silaundecane

Guidance literature:: Multi-step reaction with 6 steps

1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dichloromethane; dimethyl sulfoxide / 2 h / 20 °C

2: potassium hexamethylsilazane / tetrahydrofuran / 2 h / -78 - 20 °C

3: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 12 h / Reflux

4: palladium on activated charcoal; hydrogen / ethyl acetate / 5 h

5: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dichloromethane; dimethyl sulfoxide / 2 h / 20 °C

6: potassium hexamethylsilazane / tetrahydrofuran / -78 - 20 °C

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; palladium on activated charcoal; hydrogen; potassium hexamethylsilazane; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide; ethyl acetate; 2: |Wittig Olefination / 6: |Wittig Olefination;
DOI:10.1016/j.tetlet.2013.02.052

Reference yield:

: 1429470-12-1
3-((4S,5S)-5-((3R,5R,6S,E)-7-(tert-butyldiphenylsilyloxy)-5-(methoxymethoxy)-3,6-dimethylhept-1-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl)propan-1-ol

: 1429470-14-3
(5R,6S)-5-((2S)-4-((4S,5S)-5-(but-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-methylbutyl)-6,10,10-trimethyl-9,9-diphenyl-2,4,8-trioxa-9-silaundecane

Guidance literature:: Multi-step reaction with 3 steps

1: palladium on activated charcoal; hydrogen / ethyl acetate / 5 h

2: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dichloromethane; dimethyl sulfoxide / 2 h / 20 °C

3: potassium hexamethylsilazane / tetrahydrofuran / -78 - 20 °C

With palladium on activated charcoal; hydrogen; potassium hexamethylsilazane; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide; ethyl acetate; 3: |Wittig Olefination;
DOI:10.1016/j.tetlet.2013.02.052