(+)586-chlorobis((SS)-o-phenylenebis(methylphenylarsine))nickel(II) chloride

Base Information

Chemical Name:(+)586-chlorobis((SS)-o-phenylenebis(methylphenylarsine))nickel(II) chloride
CAS No.:77096-35-6
Molecular Formula:C₄₀H₄₀As₄ClNi*Cl
Molecular Weight:950.04
Hs Code.:

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Chemical Property of (+)586-chlorobis((SS)-o-phenylenebis(methylphenylarsine))nickel(II) chloride

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Technology Process of (+)586-chlorobis((SS)-o-phenylenebis(methylphenylarsine))nickel(II) chloride

There total 2 articles about (+)586-chlorobis((SS)-o-phenylenebis(methylphenylarsine))nickel(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: nickel(II) chloride hexahydrate

: 52120-04-4,55289-90-2,55289-91-3,57341-01-2,57375-33-4
(RR)-o-phenylenebis(methylphenylarsine)

: 77096-35-6
(+)586-chlorobis((SS)-o-phenylenebis(methylphenylarsine))nickel(II) chloride

Guidance literature:: In ethanol; to soln. (RR)-diars in ethanol added hot soln. (Ni(H2O)6)Cl2 in ethanol; soln. concd. and diluted with petroleum ether, product crystd. from ethanol upon dilution with diethyl ether; elem. anal.;

Reference yield: 49.0%

: nickel(II) chloride hexahydrate

: 52120-04-4,55289-90-2,55289-91-3,57341-01-2,57375-33-4
meso-o-phenylenebis(methylphenylarsine)

: racemic-o-phenylenebis(methylphenylarsine)

: 77059-57-5,73061-64-0,77059-56-4,77096-35-6
[Ni((RS)-o-phenylenebis(methylphenylarsine))2Cl]Cl

Guidance literature:: In ethanol; N2-atmosphere; dissoln. of mixt. of diarsine isomers in MeOH/Et2O, partial crystn. of racemic isomer on cooling, filtration, evapn. of filtrate,dissoln. in EtOH, addn. to stirred soln. of Ni-salt (in EtOH); filtration, concn. (partial crystn.), addn. of light petroleum, collection, extn. into CH2Cl2, concn., addn. of light petroleum (crystn.); elem.anal.;
DOI:10.1039/DT9790002015

Reference yield: 85.0%

: ammonium hexafluorophosphate

: 77096-35-6
(+)586-chlorobis((SS)-o-phenylenebis(methylphenylarsine))nickel(II) chloride

: 77096-37-8
(+)589-chlorobis((SS)-o-phenylenebis(methylphenylarsine))nickel(II) hexafluorophosphate

Guidance literature:: In ethanol; water; soln. NH4PF6 in water added to stirred soln. corresponding chloride in ethanol; mixt. quickly diluted with water, ppt. collected, washed with water anddried, than recrystd. from acetone-diethyl ether; elem. anal.;