Technology Process of (C5H5)Fe(C5H4C(C6H4OCH3)C(CH2CH3)C6H4OH)
There total 1 articles about (C5H5)Fe(C5H4C(C6H4OCH3)C(CH2CH3)C6H4OH) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
TiCl4; Zn;
In
tetrahydrofuran;
(Ar, Schlenk technique); addn. of TiCl4 to zinc suspn. in THF, refluxingfor 2 h, addn. of THF soln. of ferrocene deriv. in propiophenone deriv. , refluxing for 2 h; cooling to room temp., stirring with water and CH2Cl2, addn. of aq. HCl,decantation, extn. of aq. layer (CH2Cl2), drying combined CH2Cl2 phases over MgSO4, filtration, evapn., chromy. (silica gel, CH2Cl2/hexane), el em. anal.;
DOI:10.1039/b913570g
- Guidance literature:
-
With
BBr3;
In
dichloromethane;
(Ar, Schlenk technique); addn. of BBr3 to CH2Cl2 soln. of ferrocene deriv., stirring at room temp. overnight; adn. to water, extn. (CH2Cl2), drying over MgSO4, filtration, evapn., chromy. (silica gel, hexane/CH2Cl2), elem. anal.;
DOI:10.1039/b913570g
