1,1,2,2-tetra-t-butyldigermane

Base Information

• Chemical Name: 1,1,2,2-tetra-t-butyldigermane
• CAS No.: 82236-88-2
• Molecular Formula: C₁₆H₃₈Ge₂
• Molecular Weight: 375.658
• Mol file: 82236-88-2.mol

Synonyms:

Chemical Property of 1,1,2,2-tetra-t-butyldigermane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 1,1,2,2-tetra-t-butyldigermane

There total 1 articles about 1,1,2,2-tetra-t-butyldigermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

germaniumtetrachloride (10038-98-9) → tetra-t-butylgermane (66662-16-6) + 1,1,2,2-tetra-t-butyldigermane (82236-88-2)

Guidance literature:

With tert.-butyl lithium; In hexane; pentane; GeCl4 in hexane was added under dry atmosphere to a soln. of an excess of t-BuLi in pentane-hexane within 2 h in such a manner that the soln. was slightly refluxing, the mixt. was stirred for 16 h; t-Bu4Ge was not observed in the reaction; filtered, washed several times, solvents were removed, residue was heated on an oil bath to 200°C and distilled in vacuo; elem. anal.;

DOI:10.1016/S0022-328X(00)84322-3

upstream raw materials:

germaniumtetrachloride