Geraniol-D6

Base Information

• Chemical Name: Geraniol-D6
• CAS No.: 66063-44-3
• Molecular Formula: C₁₀H₁₈O
• Molecular Weight: 160.205
• Mol file: 66063-44-3.mol

Synonyms:

Chemical Property of Geraniol-D6

Chemical Property:

Purity/Quality:

Geraniol-D6 ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: Geraniol-D6 is a labelled analogue of Geraniol (G367000).

Technology Process of Geraniol-D6

There total 10 articles about Geraniol-D6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

(8,9-2H6)geranyl benzyl ether (149195-06-2) → (8,9-2H6)geraniol (66063-44-3)

Guidance literature:

With ammonia; lithium; In tetrahydrofuran; for 0.5h; Heating;

DOI:10.1021/jo00067a037

Reference yield: 91.0%

O-tert-butyldiphenylsilyl-geraniol-8,8,8,9,9,9-d6 (1161835-72-8) → (8,9-2H6)geraniol (66063-44-3)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 ℃; for 2h;

DOI:10.1002/anie.200805838

Reference yield: 76.0%

[8,8,8-2H3]-1-acetoxy-3-methyl-7-([2H3]methyl)octa-2E,6-diene → (8,9-2H6)geraniol (66063-44-3)

Guidance literature:

With potassium carbonate; In methanol; water; at 20 ℃; for 24h;

DOI:10.1002/chem.202001356

upstream raw materials:

methyl <²H₆>geranylate and nerylate

<²H₆>-6-methylhept-5-en-2-one ethylene acetal

<²H₆>-6-methylhept-5-en-2-one

(8,9-2H₆)geranyl benzyl ether

Refernces

• 1、 Raptis, Christos,Stratakis, Manolis,Garcia, Hermenegildo. "Selective isomerization of epoxides to allylic alcohols catalyzed by TiO2-supported gold nanoparticles". supporting information; experimental part. p. 3133 - 3136. Retrieved 2009/09/25.
• 2、 Pyun, Hyung-Jung,Coates, Robert M.,Wagschal, Kurt C.,McGeady, Paul,Croteau, Rodney B.. "Regiospecificity and Isotope Effects Associated with the Methyl-Methylene Eliminations in the Enzyme-Catalyzed Biosynthesis of (R)- and (S)-Limonene". . p. 3998 - 4009. Retrieved 2007/10/02.