[Ir(dtbbpy)(ppy)2][PF6]

Base Information

• Chemical Name: [Ir(dtbbpy)(ppy)2][PF6]
• CAS No.: 676525-77-2
• Molecular Formula: C₄₀H₄₀IrN₄*F₆P
• Molecular Weight: 913.969
• Mol file: 676525-77-2.mol

Synonyms:

Chemical Property of [Ir(dtbbpy)(ppy)2][PF6]

Chemical Property:

• Storage Temp.: 2-8°C

Purity/Quality:

99%, ^*data from raw suppliers

(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate >85.0%(HPLC) ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

Useful:

• Uses: [Ir(dtbbpy)(ppy)2]PF6 is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.Aryl-alkyl C?C reductive cross-coupling reactions.

Technology Process of [Ir(dtbbpy)(ppy)2][PF6]

There total 8 articles about [Ir(dtbbpy)(ppy)2][PF6] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

[iridium(III)(μ-chloro)(2-phenylpyridine)2]2 + ammonium hexafluorophosphate + 4,4'-di-tert-butyl-2,2'-bipyridine (72914-19-3) → (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate (676525-77-2)

Guidance literature:

[iridium(III)(μ-chloro)(2-phenylpyridine)2]2; 4,4'-di-tert-butyl-2,2'-bipyridine; In ethylene glycol; at 150 ℃; for 15h; Inert atmosphere;

ammonium hexafluorophosphate; In water;

DOI:10.1016/j.tetlet.2018.04.035

Reference yield: 63.0%

ammonium hexafluorophosphate + bis-(μ)-chlorotetrakis[2-(2’,4’-difluorophenyl)-5-trifluoromethylpyridinato]-(C2,N)diiridium(III) (870987-64-7) + 4,4'-di-tert-butyl-2,2'-bipyridine (72914-19-3) → (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate (676525-77-2)

Guidance literature:

bis-(μ)-chlorotetrakis[2-(2’,4’-difluorophenyl)-5-trifluoromethylpyridinato]-(C2,N)diiridium(III); 4,4'-di-tert-butyl-2,2'-bipyridine; In ethylene glycol; at 150 ℃;

ammonium hexafluorophosphate; In water; at 5 ℃;

DOI:10.1002/chem.201803144

Reference yield: 28.0%

[iridium(III)(μ-chloro)(2-phenylpyridine)2]2 + ammonium hexafluorophosphate + 4,4′-di-(tert-butyl)-2,2′-bipyridyl → (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate (676525-77-2)

Guidance literature:

[iridium(III)(μ-chloro)(2-phenylpyridine)2]2; 4,4′-di-(tert-butyl)-2,2′-bipyridyl; In ethylene glycol; at 150 ℃; for 15h; Inert atmosphere;

ammonium hexafluorophosphate; In water; Inert atmosphere;

DOI:10.1002/anie.201510014

upstream raw materials:

4,4'-di-tert-butyl-2,2'-bipyridine

silver(I) hexafluorophosphate

potassium hexafluorophosphate

bis-(μ)-chlorotetrakis[2-(2’,4’-difluorophenyl)-5-trifluoromethylpyridinato]-(C2,N)diiridium(III)

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