(η5-1-P-i-Pr2-2-NMe2-indenyl)Fe(η5-C5Me5)

Base Information

Chemical Name:(η5-1-P-i-Pr2-2-NMe2-indenyl)Fe(η5-C5Me5)
CAS No.:960058-58-6
Molecular Formula:C₂₇H₄₀FeNP
Molecular Weight:465.442
Hs Code.:

Synonyms:

Suppliers and Price of (η5-1-P-i-Pr2-2-NMe2-indenyl)Fe(η5-C5Me5)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (η5-1-P-i-Pr2-2-NMe2-indenyl)Fe(η5-C5Me5)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (η5-1-P-i-Pr2-2-NMe2-indenyl)Fe(η5-C5Me5)

There total 1 articles about (η5-1-P-i-Pr2-2-NMe2-indenyl)Fe(η5-C5Me5) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: lithium 2-NMe₂-3-P(i-Pr)2-indenide

: 4045-44-7
1,2,3,4,5-pentamethylcyclopentadiene

: iron(II) chloride

: 12126-50-0
bis(pentamethylcyclopentadienyl)iron(II)

: 960058-58-6
(η5-1-P-i-Pr2-2-NMe2-indenyl)Fe(η5-C5Me5)

Guidance literature:: With n-BuLi; In tetrahydrofuran; hexane; under N2; n-BuLi in hexane (-35°C) added to C5HMe5 in THF; stirred (ambient temp., 2 h); added to FeCl2 in THF (-35°C); stirred (2h); cooled to -35°C; Li compd. in THF (-35°C) added; stir red (ambient temp., 2 h); evapd. under vac.; residue taken up in pentane; soln. filtered through Celite; filtrate evapd. under vac.; (C5Me5)2Fe removed by sublimation; elem. anal.;
DOI:10.1021/om700832f

Reference yield:

: chloro(1,5-cyclooctadiene)rhodium(I) dimer

: 960058-58-6
(η5-1-P-i-Pr2-2-NMe2-indenyl)Fe(η5-C5Me5)

: [(η4-1,5-cyclooctadiene)Rh(κ2-P,N-3-P(i)Pr2-2-NMe2-indenide)]

Guidance literature:: In tetrahydrofuran; under N2; soln. of Rh complex in THF added to Fe complex in THF; soln. stirred at ambient temp. for 4 h;
DOI:10.1021/om700832f