tricyclo[9.2.2.1~4,8~]hexadeca-1(13),4,7,11(15)-tetraene-6,12,14,16-tetrone

Base Information

Chemical Name:tricyclo[9.2.2.1~4,8~]hexadeca-1(13),4,7,11(15)-tetraene-6,12,14,16-tetrone
CAS No.:72652-39-2
Molecular Formula:C₁₆H₁₂O₄
Molecular Weight:268.269
Hs Code.:

Synonyms:

Suppliers and Price of tricyclo[9.2.2.1~4,8~]hexadeca-1(13),4,7,11(15)-tetraene-6,12,14,16-tetrone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 2 raw suppliers

Chemical Property of tricyclo[9.2.2.1~4,8~]hexadeca-1(13),4,7,11(15)-tetraene-6,12,14,16-tetrone

Chemical Property:

Vapor Pressure:2.29E-10mmHg at 25°C

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of tricyclo[9.2.2.1~4,8~]hexadeca-1(13),4,7,11(15)-tetraene-6,12,14,16-tetrone

There total 12 articles about tricyclo[9.2.2.1~4,8~]hexadeca-1(13),4,7,11(15)-tetraene-6,12,14,16-tetrone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

: 87207-29-2
C₂₀H₂₄O₃

: 72652-39-2
<2.2>(2,5)-(2,6)-p-Benzoquinonophane

Guidance literature:: With trifluoroacetic acid; thallium(III) trifluoroacetate; for 2.5h; Ambient temperature;
DOI:10.1021/ja00360a017

Reference yield:

: 62224-04-8
2,6-bis(chloromethyl)-4-tert-butyl-anisole

: 72652-39-2
<2.2>(2,5)-(2,6)-p-Benzoquinonophane

Guidance literature:: Multi-step reaction with 6 steps

1: 50.5 percent / potassium hydroxide / benzene; ethanol; H₂O / 48 h

2: 6.90 g / m-chloroperbenzoic acid / CH₂Cl₂ / 22 h / Ambient temperature; further reagents (H₂O₂)

3: 68 percent / 450 °C / 3 Torr

4: 60 percent / BBr₃ / benzene / 47 h / Ambient temperature

5: BBr₃ / benzene

6: 35 percent / TFA, Tl(OCOCF₃)3 / 2.5 h / Ambient temperature

With potassium hydroxide; boron tribromide; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic acid; thallium(III) trifluoroacetate; In ethanol; dichloromethane; water; benzene;
DOI:10.1021/ja00360a017

Reference yield:

: 87207-27-0
8,12,15-trimethoxy-5-tert-butyl<2.2>metacyclophane

: 72652-39-2
<2.2>(2,5)-(2,6)-p-Benzoquinonophane

Guidance literature:: Multi-step reaction with 3 steps

1: 60 percent / BBr₃ / benzene / 47 h / Ambient temperature

2: BBr₃ / benzene

3: 35 percent / TFA, Tl(OCOCF₃)3 / 2.5 h / Ambient temperature

With boron tribromide; trifluoroacetic acid; thallium(III) trifluoroacetate; In benzene;
DOI:10.1021/ja00360a017