(3beta,4alpha,6xi)-3-hydroxy-15-oxo-12,13-epoxytrichothec-9-en-4-yl acetate

Base Information

Chemical Name:(3beta,4alpha,6xi)-3-hydroxy-15-oxo-12,13-epoxytrichothec-9-en-4-yl acetate
CAS No.:81331-34-2
Molecular Formula:C₁₇H₂₂O₆
Molecular Weight:322.358
Hs Code.:

Synonyms:

Suppliers and Price of (3beta,4alpha,6xi)-3-hydroxy-15-oxo-12,13-epoxytrichothec-9-en-4-yl acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of (3beta,4alpha,6xi)-3-hydroxy-15-oxo-12,13-epoxytrichothec-9-en-4-yl acetate

Chemical Property:

Vapor Pressure:2.73E-10mmHg at 25°C

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (3beta,4alpha,6xi)-3-hydroxy-15-oxo-12,13-epoxytrichothec-9-en-4-yl acetate

There total 5 articles about (3beta,4alpha,6xi)-3-hydroxy-15-oxo-12,13-epoxytrichothec-9-en-4-yl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 81331-33-1
4β-acetoxy-3α-O-(2-tetrahydropyranyl)scirpene-15-carboxaldehyde

: 81331-34-2
4β-acetoxy-3α-hydroxyscirpene-15-carboxaldehyde

Guidance literature:: With hydrogenchloride; In ethanol; for 4h; Ambient temperature;
DOI:10.1021/jm00347a018

Reference yield:

: 2270-40-8,106454-36-8,28776-47-8
anguidine

: 81331-34-2
4β-acetoxy-3α-hydroxyscirpene-15-carboxaldehyde

Guidance literature:: Multi-step reaction with 5 steps

1: 72 percent / p-toluenesulfonic acid / CH₂Cl₂ / 2 h / Ambient temperature

2: 17 percent / aq. NH₄OH / methanol; tetrahydrofuran / 168 h / Ambient temperature

3: 72 percent / pyridinium chlorochromate, sodium acetate / CH₂Cl₂ / 1 h / Ambient temperature

4: 77 percent / pyridine / 3.5 h / Ambient temperature

5: 45 percent / 1 N aq. HCl / aq. ethanol / 4 h / Ambient temperature

With pyridine; hydrogenchloride; ammonium hydroxide; sodium acetate; toluene-4-sulfonic acid; pyridinium chlorochromate; In tetrahydrofuran; methanol; ethanol; dichloromethane;
DOI:10.1021/jm00347a018

Reference yield:

: 81331-31-9
4β-hydroxy-3α-O-(2-tetrahydropyranyl)scirpene-15-carboxaldehyde

: 81331-34-2
4β-acetoxy-3α-hydroxyscirpene-15-carboxaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 77 percent / pyridine / 3.5 h / Ambient temperature

2: 45 percent / 1 N aq. HCl / aq. ethanol / 4 h / Ambient temperature

With pyridine; hydrogenchloride; In ethanol;
DOI:10.1021/jm00347a018