3,8-Dioxatricyclo[3.2.1.02,4]oct-6-ylmethanol

Base Information

Chemical Name:3,8-Dioxatricyclo[3.2.1.02,4]oct-6-ylmethanol
CAS No.:90049-70-0
Molecular Formula:C₇H₁₀O₃
Molecular Weight:142.155
Hs Code.:
NSC Number:100898
DSSTox Substance ID:DTXSID80295270

Synonyms:90049-70-0;3,8-dioxatricyclo[3.2.1.02,4]oct-6-ylmethanol;NSC100898;NCIOpen2_001799;SCHEMBL13135738;DTXSID80295270;NSC-100898

Suppliers and Price of 3,8-Dioxatricyclo[3.2.1.02,4]oct-6-ylmethanol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 3,8-Dioxatricyclo[3.2.1.02,4]oct-6-ylmethanol

Chemical Property:

Vapor Pressure:0.0016mmHg at 25°C
XLogP3:-0.6
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:142.062994177
Heavy Atom Count:10
Complexity:170

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1C(C2C3C(C1O2)O3)CO

Technology Process of 3,8-Dioxatricyclo[3.2.1.02,4]oct-6-ylmethanol

There total 5 articles about 3,8-Dioxatricyclo[3.2.1.02,4]oct-6-ylmethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 81763-39-5,81800-81-9,92936-00-0,92936-01-1
methyl (+/-)-exo-3,8-dioxatricylo<3.2.1.0^2,4>oktane-6exo-carboxylate

: 90049-70-0
(1R,2R,4S,5S,6R)-1-(3,8-Dioxa-tricyclo[3.2.1.0^2,4]oct-6-yl)-methanol

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; for 1h; Yield given; Ambient temperature;
DOI:10.1016/0008-6215(88)85054-7

Reference yield:

: 24363-23-3,38263-45-5,38263-46-6,64589-22-6,90760-55-7,90760-56-8,117772-64-2
(+/-)-7-oxabicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid

: 90049-70-0
(1R,2R,4S,5S,6R)-1-(3,8-Dioxa-tricyclo[3.2.1.0^2,4]oct-6-yl)-methanol

Guidance literature:: Multi-step reaction with 3 steps

1: 96 percent / acetyl chloride / 3 h / Ambient temperature

2: 83 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 2 h / Ambient temperature

3: lithium aluminum hydride / tetrahydrofuran / 1 h / Ambient temperature

With lithium aluminium tetrahydride; acetyl chloride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1016/0008-6215(88)85054-7

Reference yield:

: 17791-32-1,17791-33-2,21987-33-7,88517-51-5,88517-52-6,204988-60-3
exo-7-oxabicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester

: 90049-70-0
(1R,2R,4S,5S,6R)-1-(3,8-Dioxa-tricyclo[3.2.1.0^2,4]oct-6-yl)-methanol

Guidance literature:: Multi-step reaction with 2 steps

1: 83 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 2 h / Ambient temperature

2: lithium aluminum hydride / tetrahydrofuran / 1 h / Ambient temperature

With lithium aluminium tetrahydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1016/0008-6215(88)85054-7