hexafluorophosphate

Base Information

• Chemical Name: hexafluorophosphate
• CAS No.: 870987-63-6
• Molecular Formula: C₄₂H₃₄F₁₀IrN₄*F₆P
• Molecular Weight: 1121.93
• Hs Code.: 2843909000
• Mol file: 870987-63-6.mol

Synonyms:

Chemical Property of hexafluorophosphate

Chemical Property:

• Melting Point: >300 °C
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Solubility.: Chloroform (Slightly)

Purity/Quality:

99%, ^*data from raw suppliers

[4,?4''-?Bis(tert-butyl)?-?2,?2''-?bipyridine]?bis[3,?5-?difluoro-?2-?[5-?(trifluoromethyl)?-?2-?pyridinyl]?phenyl]?iridium(III)hexafluorophosphate ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

Useful:

• Uses: (Ir[dF(CF3)ppy]2(dtbpy))PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.It has been used to achieve late-stage incorporation of alkyl groups to a variety of biologically active heterocycles. [4,?4''-?Bis(tert-butyl)?-?2,?2''-?bipyridine]?bis[3,?5-?difluoro-?2-?[5-?(trifluoromethyl)?-?2-?pyridinyl]?phenyl]?iridium(III) hexafluorophosphate is commonly used as a catalyst in the synthesis of various compounds such as saturated N-?heterocycles from aldehydes, fosmidomycin analogue, and many more.

Technology Process of hexafluorophosphate

There total 5 articles about hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

ammonium hexafluorophosphate + bis-(μ)-chlorotetrakis[2-(2’,4’-difluorophenyl)-5-trifluoromethylpyridinato]-(C2,N)diiridium(III) (870987-64-7) + 4,4'-di-tert-butyl-2,2'-bipyridine (72914-19-3) → [Ir(df(CF3)ppy)2(dtbbpy)]PF6 (870987-63-6)

Guidance literature:

bis-(μ)-chlorotetrakis[2-(2’,4’-difluorophenyl)-5-trifluoromethylpyridinato]-(C2,N)diiridium(III); 4,4'-di-tert-butyl-2,2'-bipyridine; In ethylene glycol; at 150 ℃; for 18h; Inert atmosphere;

ammonium hexafluorophosphate; In water; for 0.333333h; Cooling with ice;

DOI:10.1021/acs.joc.5b01193

Reference yield: 74.0%

ammonium hexafluorophosphate + bis-(μ)-chlorotetrakis[2-(2’,4’-difluorophenyl)-5-trifluoromethylpyridinato]-(C2,N)diiridium(III) (870987-64-7) + 4,4'-di-tert-butyl-2,2'-bipyridine (72914-19-3) → [Ir(df(CF3)ppy)2(dtbbpy)]PF6 (870987-63-6)

Guidance literature:

bis-(μ)-chlorotetrakis[2-(2’,4’-difluorophenyl)-5-trifluoromethylpyridinato]-(C2,N)diiridium(III); 4,4'-di-tert-butyl-2,2'-bipyridine; In ethylene glycol; at 150 ℃; for 24h; Inert atmosphere;

ammonium hexafluorophosphate; In water;

DOI:10.1016/j.tet.2019.130641

Reference yield: 70.0%

ammonium hexafluorophosphate + 2-(2',4'-difluorophenyl)-5-(trifluoromethyl)pyridine (387827-64-7) + iridium(III) chloride monohydrate + 4,4'-di-tert-butyl-2,2'-bipyridine (72914-19-3) → [Ir(df(CF3)ppy)2(dtbbpy)]PF6 (870987-63-6)

Guidance literature:

2-(2',4'-difluorophenyl)-5-(trifluoromethyl)pyridine; iridium(III) chloride monohydrate; In ethylene glycol; at 20 - 200 ℃; for 0.85h; Microwave irradiation;

4,4'-di-tert-butyl-2,2'-bipyridine; In ethylene glycol; at 200 ℃; for 0.5h; Microwave irradiation;

ammonium hexafluorophosphate; In water;

DOI:10.1002/chem.201803144

upstream raw materials:

bis-(μ)-chlorotetrakis[2-(2’,4’-difluorophenyl)-5-trifluoromethylpyridinato]-(C2,N)diiridium(III)

4,4'-di-tert-butyl-2,2'-bipyridine

2-(2',4'-difluorophenyl)-5-(trifluoromethyl)pyridine

potassium hexafluorophosphate

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 870987-63-6 hexafluorophosphate

Send

Send

Metric Ton KG G Pound L ML

Send

Send