cis,cis-1,2,5-trimethyl-2-(3-oxobutyl)bicyclo<3.3.0>octan-3-one

Base Information

Chemical Name:cis,cis-1,2,5-trimethyl-2-(3-oxobutyl)bicyclo<3.3.0>octan-3-one
CAS No.:71519-46-5
Molecular Formula:C₁₅H₂₄O₂
Molecular Weight:236.354
Hs Code.:

Synonyms:

Suppliers and Price of cis,cis-1,2,5-trimethyl-2-(3-oxobutyl)bicyclo<3.3.0>octan-3-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of cis,cis-1,2,5-trimethyl-2-(3-oxobutyl)bicyclo<3.3.0>octan-3-one

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

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Technology Process of cis,cis-1,2,5-trimethyl-2-(3-oxobutyl)bicyclo<3.3.0>octan-3-one

There total 28 articles about cis,cis-1,2,5-trimethyl-2-(3-oxobutyl)bicyclo<3.3.0>octan-3-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.5%

: 78012-48-3,78086-41-6
C₁₈H₃₂O₂Si

: 71519-46-5
cis,cis-1,2,5-trimethyl-2-(3-oxobutyl)bicyclo<3.3.0>octan-3-one

Guidance literature:: With sulfuric acid; In methanol; Heating;
DOI:10.1021/ja00397a043

Reference yield: 92.0%

: (1R,3aR,6aR)-1,3a,6a-Trimethyl-1-[2-(2-methyl-[1,3]dioxolan-2-yl)-ethyl]-hexahydro-pentalen-2-one

: 71519-46-5
cis,cis-1,2,5-trimethyl-2-(3-oxobutyl)bicyclo<3.3.0>octan-3-one

Guidance literature:: With hydrogenchloride; In acetone; for 1h; Heating;
DOI:10.1021/ja00372a016

Reference yield:

: 74629-83-7,74629-84-8,80906-77-0,80906-78-1
(3aR,6aR)-1-Allyl-1,3a,6a-trimethyl-octahydro-pentalen-2-ol

: 71519-46-5
cis,cis-1,2,5-trimethyl-2-(3-oxobutyl)bicyclo<3.3.0>octan-3-one

Guidance literature:: Multi-step reaction with 10 steps

1: 1.) KH / tetrahydrofuran / 18 h / Heating

2: 1.) B₂H₆, 2.) NaOH-H₂O₂ / 1.) THF, RT, 18 h, 2.) THF-H₂O, 0,5 h

3: CrO₃-dipyridine complex / CH₂Cl₂ / 0.5 h / Ambient temperature

4: p-toluenesulfonic acid hydrate / benzene / 18 h / Heating

5: 62 percent / Li / liquid ammonia; tetrahydrofuran / -33 °C

6: 77 percent / CrO₃-dipyridine complex / CH₂Cl₂

7: 100 percent / 1.2 N hydrochloric acid / acetone / 3 h / Heating

8: 92 percent / 6 N chromic acid / acetone / 0.17 h / Ambient temperature

9: 64 percent / Ac₂O, HClO₄ / CH₂Cl₂ / 0.33 h

10: 41 percent / diethyl ether / 17 h

With hydrogenchloride; sodium hydroxide; perchloric acid; dihydrogen peroxide; acetic anhydride; chromic acid; lithium; potassium hydride; dipyridine chromium trioxide; toluene-4-sulfonic acid; diborane; In tetrahydrofuran; diethyl ether; dichloromethane; ammonia; acetone; benzene;
DOI:10.1021/ja00372a016