diamantane-1,4-diol

Base Information

• Chemical Name: diamantane-1,4-diol
• CAS No.: 77076-31-4
• Molecular Formula: C₁₄H₂₀O₂
• Molecular Weight: 220.312
• Mol file: 77076-31-4.mol

Synonyms:

Chemical Property of diamantane-1,4-diol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diamantane-1,4-diol

There total 5 articles about diamantane-1,4-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

diamantane (2292-79-7) → diamantan-1-ol (30545-19-8) + diamantane-1,4-diol (77076-31-4)

Guidance literature:

diamantane; With nitric acid; In dichloromethane; at 20 ℃; for 16h;

With water; In dichloromethane; for 2h; Further stages.; Heating;

DOI:10.1002/ejoc.200700378

Reference yield: 32.0%

1,4-dinitroxydiamantane → diamantane-1,4-diol (77076-31-4)

Guidance literature:

With water;

DOI:10.1134/S1070428021020081

Reference yield:

diamantane (2292-79-7) → diamantane-1,4-diol (77076-31-4)

Guidance literature:

Multi-step reaction with 3 steps

1: nitric acid / 24 h / 20 °C

2: nitric acid

3: water

With water; nitric acid;

DOI:10.1134/S1070428021020081

upstream raw materials:

diamantane

1-nitroxydiamantane

Refernces

• 1、 Fokina, Natalie A.,Tkachenko, Boryslav A.,Merz, Anika,Serafin, Michael,Dahl, Jeremy E. P.,Carlson, Robert M. K.,Fokin, Andrey A.,Schreiner, Peter R.. "Hydroxy derivatives of diamantane, triamantane, and [121]tetramantane: Selective preparation of bis-apical derivatives". . p. 4738 - 4745. Retrieved 2008/03/13.