Tris(2,2'-Bipyrazine)Ruthenium(II) Hexafluorophosphate

Base Information

Chemical Name:Tris(2,2'-Bipyrazine)Ruthenium(II) Hexafluorophosphate
CAS No.:80907-56-8
Molecular Formula:C₃H₆O*C₂₄H₁₈N₁₂Ru*2F₆P
Molecular Weight:952.606
Hs Code.:28439000
European Community (EC) Number:815-118-5

Synonyms:80907-56-8;Tris(2,2'-Bipyrazine)Ruthenium(II) Hexafluorophosphate;lambda2-ruthenium(2+) ion tris(2-(pyrazin-2-yl)pyrazine) bis(hexafluoro-lambda5-phosphanuide);EN300-7391507;2-pyrazin-2-ylpyrazine;ruthenium(2+);dihexafluorophosphate;-ruthenium(2+) tris(2,2'-bipyrazine) bis(hexafluoro--phosphanuide);lambda(2)-ruthenium(2+) tris(2,2'-bipyrazine) bis(hexafluoro-lambda-phosphanuide)

Suppliers and Price of Tris(2,2'-Bipyrazine)Ruthenium(II) Hexafluorophosphate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
Tris(2,2'-bipyrazine)ruthenium(II) hexafluorophosphate, 95%
50mg
$ 58.00

Strem Chemicals
Tris(2,2'-bipyrazine)ruthenium(II) hexafluorophosphate, 95%
250mg
$ 232.00

Sigma-Aldrich
[Ru(bpz)3][PF6]2 95%
100mg
$ 137.00

Sigma-Aldrich
[Ru(bpz)3][PF6]2 95%
50mg
$ 72.00

Crysdot
[Ru(bpz)3][PF6]2 95+%
250mg
$ 327.00

Crysdot
[Ru(bpz)3][PF6]2 95+%
1g
$ 909.00

ChemSupplyAustralia
Tris(2,?2'-?Bipyrazine)ruthenium(II) hexafluorophosphate, 95%
1 g
$ 785.00

ChemSupplyAustralia
Tris(2,?2'-?Bipyrazine)ruthenium(II) hexafluorophosphate, 95%
250 mg
$ 245.00

ChemSupplyAustralia
Tris(2,?2'-?Bipyrazine)ruthenium(II) hexafluorophosphate, 95%
50 mg
$ 65.00

Arctom
[Ru(bpz)3][PF6]2 98%
250mg
$ 302.00

Total 20 raw suppliers

Chemical Property of Tris(2,2'-Bipyrazine)Ruthenium(II) Hexafluorophosphate

Chemical Property:

Melting Point:162-210°C (The MP data is a DECOMP) (lit.)
Storage Temp.:Inert atmosphere,Room Temperature
Sensitive.:air sensitive
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:26
Rotatable Bond Count:3
Exact Mass:866.010441
Heavy Atom Count:51
Complexity:186

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tris(2,2'-bipyrazine)ruthenium(II) hexafluorophosphate, 95% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 36/37/38
Safety Statements: 26

MSDS Files:

Useful:

Canonical SMILES:C1=CN=C(C=N1)C2=NC=CN=C2.C1=CN=C(C=N1)C2=NC=CN=C2.C1=CN=C(C=N1)C2=NC=CN=C2.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[Ru+2]
Uses [Ru(bpz)3][PF6]2 may be employed as a photocatalyst during the preparation of cyclopentylamine derivatives, via visible light-assisted cycloaddition reaction of N-arylcyclopropylamines with styrene derivatives. It may also be employed for the photocatalytic synthesis of trans-substituted cyclohexene derivative.

Technology Process of Tris(2,2'-Bipyrazine)Ruthenium(II) Hexafluorophosphate

There total 1 articles about Tris(2,2'-Bipyrazine)Ruthenium(II) Hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 17084-13-8
potassium hexafluorophosphate

: 80925-50-4
Ru(C₈H₆N₄)3⁽²⁺⁾*2Cl^(1-)*3.5H₂O=Ru(C₈H₆N₄)3Cl₂*3.5H₂O

: 80907-56-8
Ru(C₈H₆N₄)3⁽²⁺⁾*2PF₆^(1-)*1.5(CH₃)2CO=Ru(C₈H₆N₄)3(PF₆)2*1.5(CH₃)2CO

Guidance literature:: In water; aq. KPF6 was added to a boiling soln. of complex; filtration, washing a ppt. with water, dissolving in acetone/ethanol, concn. for crystn.;
DOI:10.1021/ic00136a030

Reference yield: 44.0%

: 80907-56-8
Ru(C₈H₆N₄)3⁽²⁺⁾*2PF₆^(1-)*1.5(CH₃)2CO=Ru(C₈H₆N₄)3(PF₆)2*1.5(CH₃)2CO

: 68696-18-4
tetraethylammonium chloride monohydrate

: 80907-59-1
Ru(C₈H₆N₄)2Cl₂*H₂O

Guidance literature:: In acetonitrile; Irradiation (UV/VIS); ammonium chloride was added to a stirred soln. of complex with irradiation over 15 min, irradiated for 16 h; filtration, concn., washing a ppt. with acetonitrile, recrystn. (acetonitrile);
DOI:10.1021/ic00136a030