(2-Bromophenyl)dicyclohexylphosphine

Base Information

Chemical Name:(2-Bromophenyl)dicyclohexylphosphine
CAS No.:757958-40-0
Molecular Formula:C₁₈H₂₆BrP
Molecular Weight:353.282
Hs Code.:
European Community (EC) Number:693-129-2
Mol file:757958-40-0.mol

Synonyms:(2-bromophenyl)dicyclohexylphosphine;757958-40-0;(2-BROMOPHENYL)DICYCLOHEXYLPHOSPHANE;starbld0041614;SCHEMBL1683364;(2-Bromophenyl)dicyclohexylphosphine, 97%

Suppliers and Price of (2-Bromophenyl)dicyclohexylphosphine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
(2-Bromophenyl)dicyclohexylphosphine 97%
5g
$ 494.00

Sigma-Aldrich
(2-Bromophenyl)dicyclohexylphosphine 97%
1g
$ 124.00

Total 5 raw suppliers

Chemical Property of (2-Bromophenyl)dicyclohexylphosphine

Chemical Property:

Melting Point:76-79°C
XLogP3:5.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:352.09555
Heavy Atom Count:20
Complexity:263

Purity/Quality:

98%,99%, ^*data from raw suppliers

(2-Bromophenyl)dicyclohexylphosphine 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1CCC(CC1)P(C2CCCCC2)C3=CC=CC=C3Br

Technology Process of (2-Bromophenyl)dicyclohexylphosphine

There total 2 articles about (2-Bromophenyl)dicyclohexylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 583-55-1
1-Bromo-2-iodobenzene

: 829-84-5
dicyclohexylphosphane

: 757958-40-0
(ortho-bromophenyl)dicyclohexylphosphine

Guidance literature:: With caesium carbonate; palladium diacetate; In 1,4-dioxane; at 80 ℃; for 18h;
DOI:10.1016/j.tet.2004.05.044

Reference yield:

: 583-55-1
1-Bromo-2-iodobenzene

: 16523-54-9
chlorodicyclohexylphosphane

: 757958-40-0
(ortho-bromophenyl)dicyclohexylphosphine

Guidance literature:: 1-Bromo-2-iodobenzene; With isopropylmagnesium chloride; In tetrahydrofuran;

chlorodicyclohexylphosphane; In tetrahydrofuran;
DOI:10.1002/anie.201002225

Reference yield:

: 757958-40-0
(ortho-bromophenyl)dicyclohexylphosphine

: ((phenylboranediyl)bis(2,1-phenylene))bis(dicyclohexylphosphine)

Guidance literature:: Multi-step reaction with 2 steps

1: n-butyllithium / diethyl ether / 2 h / -78 - 20 °C

2: toluene / 5 h / -78 °C / Inert atmosphere

With n-butyllithium; In diethyl ether; toluene;
DOI:10.3762/bjoc.12.152